| KOH活化的炭干凝胶及其储氢性能 |
| KOH-Activated Carbon Xerogels for Hydrogen Storage |
| 作者 | 单位 | E-mail | | 张静娴 | 暨南大学化学系,纳米化学研究所,广州 510632 | | | 易观贵 | 暨南大学化学系,纳米化学研究所,广州 510632 | | | 刘应亮 | 暨南大学化学系,纳米化学研究所,广州 510632 | tliuyl@jnu.edu.cn | | 吴拥建 | 暨南大学化学系,纳米化学研究所,广州 510632 | | | 肖勇 | 暨南大学化学系,纳米化学研究所,广州 510632 | | | 孙立贤 | 中科院大连化学物理研究所,大连 116023 | |
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| 摘要: 以苯二酚与甲醛为前驱体,赖氨酸作为催化剂,快速合成了有机溶胶.有机溶胶经碳化以及KOH进一步活化,获得了具有较高微孔率和较大比表面积的炭干凝胶.研究了多孔炭干凝胶的储氢性能,比较了不同活化程度的炭干凝胶的最大储氢容量与比表面积、微孔体积以及微孔孔径分布的关系.结果表明,KOH适度活化的炭干凝胶(ACX-5)具有较高的比表面积(2 204 m2·g-1) 和较大的总孔容积(1.09 cm3·g-1),在77 K和1.1 MPa氢压下时其储氢量可达4.3wt%. |
| 关键词: 炭干凝胶 KOH活化 储氢 |
| 基金项目: 国家-广东联合基金(No.U0734005);中央高校基本科研业务费专项资金(No.21610102);国家自然科学基金(No.21031001);广东省高等学校科技创新重点项目(No.cxzd1014)资助项目. |
| Abstract: Organic xerogel was rapidly prepared via a lysine-catalyzed gelation process with resorcinol and formaldehyde as the precursors. After carbonization and a subsequent activation with KOH, carbon xerogels with high microporosity and high-specific-surface area could be obtained. The hydrogen storage properties of the porous carbon xerogels were studied. The relationship of the maximum hydrogen storage capacity with specific surfacearea, micropore volume and pore size distribution was investigated. The results show that moderately KOH-activated carbon xerogel (ACX-5) with high surface area of 2 204 m2·g-1 and large total-pore volume of 1.09 cm3·g-1 exhibits the largest hydrogen storage capacity of 4.3wt% at 77 K and under 1.1 MPa hydrogen pressure. |
| Keywords: carbon xerogels KOH activation hydrogen storage |
| 投稿时间：2011-11-28 修订日期：2012-06-02 |
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| 张静娴,易观贵,刘应亮,吴拥建,肖勇,孙立贤.KOH活化的炭干凝胶及其储氢性能[J].无机化学学报,2012,28(12):2565-@. |
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