| 以2,4’-联苯二羧酸及咪唑并[4,5-f][1,10]邻菲咯啉为配体的钴(Ⅱ)、锰(Ⅱ)配合物的水热合成及晶体结构 | |
| Syntheses and Crystal Structures of Co(Ⅱ) and Mn(Ⅱ) Complexes with 2,4’-Biphenyldicarboxylic Acid and Imidazo[4,5-f][1,10]phenanthroline Ligands | |
| 摘要: 在水热条件下,以2,4'-联苯二羧酸(2,4'-H2bpdc)和咪唑并[4,5-f][1,10]邻菲咯啉(L)为配体构筑了两种配合物{[Co(2,4'-bpdc)(L)(H2O)]·H2O}n (1)和[Mn(2,4'-bpdc)(L)(H2O)]n (2),并利用元素分析、X-射线单晶衍射和热重分析对其结构进行了表征。配合物1具有一维链状结构,配合物2展示了一维双链结构,两个配合物都通过分子间氢键和π-π相互作用形成三维网状结构。 | |
| 关键词: 钴(Ⅱ)配合物 锰(Ⅱ)配合物 2,4’-联苯二羧酸 咪唑并[4,5-f][1,10]邻菲咯啉 晶体结构 | |
| 基金项目: 国家自然科学基金(No.60978059)和教育部新世纪优秀人才(No.NCET-10-0176)资助项目。 | |
| Abstract: Two complexes constructed with 2,4'-biphenyldicarboxylic acid (2,4'-H2bpdc), 1,10-phenanthroline derivative ligands and metallic salts, namely, {[Co(2,4'-bpdc)(L)(H2O)]·H2O}n (1), [Mn(2,4'-bpdc)(L)(H2O)]n (2) (L=imidazo[4,5-f][1,10]phenanthroline) were synthesized under hydrothermal reaction. The complexes are characterized by elemental analysis, single crystal X-ray diffraction and thermogravimetric analysis. Complex 1 has a 1D chain structure. Complex 2 forms a one-dimensional double-chain structure. They both further linked into a three-dimensional net structure via the intermolecular hydrogen bonds and aromatic π-π interactions. CCDC: 934719, 1; 934720,2. | |
| Keywords: cobalt(Ⅱ) complex manganese(Ⅱ) complex 2,4’-biphenyldicarboxylic acid imidazo[4,5-f][1,10]phenanthroline crystal structure | |
| 投稿时间：2012-06-26 修订日期：2013-02-02 | |
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| 刘春波,赵晗,王珊珊,查小林,李秀颖,车广波.以2,4’-联苯二羧酸及咪唑并[4,5-f][1,10]邻菲咯啉为配体的钴(Ⅱ)、锰(Ⅱ)配合物的水热合成及晶体结构[J].无机化学学报,2013,29(7):1533-1538. | |
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