| 以吡啶为配体的镍配合物[Ni(py)3(H2O)3](1,5-nds)的合成、晶体结构及性质 |
| Synthesis, Crystal Structure and Properties of Nickel Complex Containing Pyridine [Ni(py)3(H2O)3](1,5-nds) |
| 作者 | 单位 | E-mail | | 关磊 | School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China | gl_mater@163.com | | 王莹 | Center of Experiment, College of Chemistry, Chemical Engineering and Environment Engineering, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China | | | 吕山 | School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China | | | 张忠金 | School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China | | | 范文婷 | School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China | | | 高威 | School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China | |
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| 摘要: 采用缓慢蒸发法,在水溶剂中合成了含氮配体单核Ni(Ⅱ)配合物[Ni(py)3(H2O)3](1,5-nds)(py=pyridine,1,5-nds=1,5-萘二磺酸根离子)。采用X射线单晶衍射、红外光谱、热分析和紫外可见光谱等方法对配合物进行了表征。X射线单晶衍射表征结果表明,该配合物晶体属于单斜晶系,空间群为C2/c。晶体学参数:a=1.56946(17)nm,b=1.21995(12)nm,c=1.45471(16)nm,β=14.5471(16)°,V=2.7651(5)nm3,Z=4。考察了该配合物的磁性和荧光性质。 |
| 关键词: 镍离子 配合物 热稳定性 晶体结构 吡啶 |
| 基金项目: 辽宁石油化工大学博士科研启动经费(No.2011XJJ-033),辽宁石油化工大学创新训练资助项目 |
| Abstract: The mononuclear containing N-donor ligand Ni(Ⅱ) complex [Ni(py)3(H2O)3](1,5-nds) (py=pyridine, 1,5-nds=1,5-naphthalene-disulfonate anion) was synthesized by slow evaporation method in water. It was characterized by X-ray crystal diffraction, IR, thermal analysis, UV-Vis spectroscopy, etc. The characterization results of X-ray single crystal diffraction show that the crystal of the complex crystallized in monoclinic system with space group C2/c. The unit cell parameters include a=1.56946(17) nm, b=1.21995(12) nm, c=1.45471(16) nm, β=14.5471(16)°, V=2.7651(5) nm3, Z=4. The magnetic and fluorescent properties of the complex were studied. CCDC: 947286. |
| Keywords: nickel anion complex thermal stability property crystal structure pyridine |
| 投稿时间：2012-08-04 修订日期：2013-05-05 |
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| 关磊,王莹,吕山,张忠金,范文婷,高威.以吡啶为配体的镍配合物[Ni(py)3(H2O)3](1,5-nds)的合成、晶体结构及性质[J].无机化学学报,2013,29(10):2079-2084. |
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