| 模板分子诱导的微孔镧系-2-羧基肉桂酸超分子配合物的合成与结构 |
| Templating Synthesis and Structures of Microporous Lanthanide Supramolecular Complexes Based on 2-Carboxycinnamic Acid |
| 作者 | 单位 | E-mail | | 孙长艳 | Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China | cysun@ustb.edu.cn | | 李杨 | Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China | | | 李文军 | Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China | | | 车平 | Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China | |
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| 摘要: 由水热法合成了2个微孔镧系超分子配合物[Ln(CCA)(OH)(phen)(H2O)]n·n(phen)·nH2O(Ln=Yb,1;Er,2;H2CCA=2-羧基肉桂酸;phen=1,10-菲啰啉),并用元素分析、IR及X-射线单晶衍射对其进行了表征。晶体结构研究表明,2个配合物都是由配体2-羧基肉桂酸连接而形成的一维双链结构,该链状结构通过氢键和π-π堆积作用扩展为具有微孔结构的超分子。1,10-菲啰啉在微孔结构的形成过程中起到了模板剂的作用。 |
| 关键词: 2-羧基肉桂酸 镧系金属配合物 微孔结构 模板分子 |
| 基金项目: 国家自然科学基金(No.21101013),中央高校基本科研业务费专项资金(No.FRF-SD-13-002B)资助项目 |
| Abstract: Two microporous lanthanide supramolecular complexes [Ln(CCA)(OH)(phen)(H2O)]n·n(phen)·nH2O(Ln=Yb, 1; Er, 2; H2CCA=2-carboxycinnamic acid; phen=1,10-phenanthraline) were obtained through hydrothermal reaction and characterized by elemental analysis, IRand single-crystal X-ray diffraction. The results show that the two complexes are isostructural and in the two complexes, dinuclear Ln2(OH)2 units are linked by CCA2-ligands to form 1Dinfinite double-stranded chains. There are two kinds of phen ligands. One adopts a chelating-bidentate coordination mode, the other is not involved in the coordination and acts as templating ligands, which leads to the formation of supramolecular networks with microporous structures. CCDC: 917027, 1; 917028, 2. |
| Keywords: 2-carboxycinnamic acid lanthanide complex microporous structure template |
| 投稿时间：2012-12-28 修订日期：2013-06-16 |
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| 孙长艳,李杨,李文军,车平.模板分子诱导的微孔镧系-2-羧基肉桂酸超分子配合物的合成与结构[J].无机化学学报,2013,29(10):2140-2144. |
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