| 以对苯二甲酸及咪唑并[4,5-f][1,10]邻菲咯啉为配体的镉(Ⅱ)、锌(Ⅱ)配合物的构筑及晶体结构 |
| Hydrothermal Syntheses and Crystal Structures of Cd(Ⅱ) and Zn(Ⅱ) Complexes Constructed with 1,4-Benzenedicarboxylic Acid and Imidazo[4,5-f][1,10]phenanthroline Ligands |
| 作者 | 单位 | E-mail | | 车广波 | Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Chinese Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China | guangbochejl@yahoo.com | | 李微微 | College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China | | | 王珊珊 | College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China | | | 王丹 | State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, Guangdong 510640, China | | | 赵晗 | College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China | | | 刘春波 | Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Chinese Ministry of Education, Jilin Normal University, Siping, Jilin 136000, China
College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China | |
|
| 摘要: 在水热条件下,以对苯二甲酸(H2bdc)和咪唑并[4,5-f][1,10]邻菲咯啉(Imphen)为配体构筑了两种配合物[Cd(bdc)(Imphen)(H2O)]n·nH2O(1)和[Zn(bdc)(Imphen)(H2O)]n·nH2O(2),并利用元素分析和X-射线单晶衍射对其结构进行了表征。结构分析表明:bdc2-在2个配合物中展示了不同的配位模式,配合物1和2都具有一维链状结构,并且都通过分子间氢键和π-π相互作用形成三维网状结构。此外,对配合物的热稳定性和发光性质也进行了研究。 |
| 关键词: 镉(Ⅱ)配合物 锌(Ⅱ)配合物 对苯二甲酸 咪唑并[4,5-f][1,10]邻菲咯啉 晶体结构 |
| 基金项目: 教育部新世纪优秀人才(No.NCET-10-0176)资助项目 |
| Abstract: Two novel metal-organic frameworks (MOFs), [Cd(bdc)(Imphen)(H2O)]n·nH2O (1) and [Zn(bdc)(Imphen)(H2O)]n·nH2O (2) based on 1,4-benzenedicarboxylic acid (H2bdc) and imidazo[4,5-f][1,10]phenanthroline (Imphen) ligands, have been constructed under hydrothermal conditions. The complexes are characterized by elemental analyse, single crystal X-ray diffraction. Structural analyses show that the complexes1 and b>2 all present one dimensional chain and bdc2- ligands display different coordination modes. Furthermore, the adjacent chains are further connected by the hydrogen-bonding and π-π stacking interactions generating three-dimensional supramolecular structures. In addition, thermal stability and luminescent properties of two complexes were also investigated. CCDC: 947287, 1; 947288, 2. |
| Keywords: cadmium(Ⅱ) complex zinc(Ⅱ) complex 1,4-benzenedicarboxylic acid imidazo[4,5-f][1,10]phenanthroline crystal structure |
| 投稿时间：2012-12-01 修订日期：2013-04-28 |
| 摘要点击次数: 1858 |
| 全文下载次数: 1205 |
| 车广波,李微微,王珊珊,王丹,赵晗,刘春波.以对苯二甲酸及咪唑并[4,5-f][1,10]邻菲咯啉为配体的镉(Ⅱ)、锌(Ⅱ)配合物的构筑及晶体结构[J].无机化学学报,2013,29(10):2188-2194. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
