| 1, 1, 4, 7, 7-五(2-苯并咪唑甲基)二乙基三胺镍(Ⅱ)配合物的合成, 晶体结构和SOD活性研究 | |
| Synthesis, Crystal Structure and SOD Activity of Ni(Ⅱ) Complex with1, 1, 4, 7, 7-Pentakis (1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane | |
| 摘要: 合成和表征了标题配合物[Ni(DTPB)H2Cl]Cl(BF4)2·4H2O(DTPB为1,1,4,7,7-五(2'-苯并咪唑甲基)-二乙基三胺）,并用紫外光谱研究了它的超氧化物歧化酶(SOD)模拟活性。结果表明:配合物为六配位的变形八面体构型,它能较好地抑制邻苯三酚的氧化,IC50值为29.8mg·L-1,且反应温度和pH值影响其SOD活性。 | |
| 关键词: 镍(Ⅱ)配合物 苯并咪唑 晶体结构 SOD活性 | |
| 基金项目: 国家自然科学基金(No.51173060)资助项目。 | |
| Abstract: The title complex [Ni(DTPB)H2Cl]Cl(BF4)2·4H2O (DTPB＝1, 1, 4, 7, 7-pentakis(1H-benzimidazol-2-ylmethyl)-1, 4, 7-triazaheptane) has been synthesized and structurally characterized, and its superoxide dismutase (SOD) catalytic activity was investigated by UVspectra. The results showed that the title complex exhibited distorted octahedron geometry, it can inhibit pyrogallol oxidation, IC50 of the complex was 29.8 mg·L-1, and its SOD activity was affected by reaction temperatures and pH values. CCDC: 606551. | |
| Keywords: nickel(Ⅱ) complex benzimidazole crystal structure SOD activity | |
| 投稿时间：2013-02-20 修订日期：2013-05-03 | |
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| 全文下载次数: 1918 | |
| 张勇,胡家尾,周霞,陈世明,马志刚,陈雪梅.1, 1, 4, 7, 7-五(2-苯并咪唑甲基)二乙基三胺镍(Ⅱ)配合物的合成, 晶体结构和SOD活性研究[J].无机化学学报,2013,29(11):2491-2496. | |
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