| 含二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸的Co(Ⅱ)配合物的合成、晶体结构及光催化性能研究 | |
| Synthesis, Crystal Structure and Photocatalytic Property of Co(Ⅱ) Compound with Dipyrido[3,2-a∶2’,3’-c]-phenazine-2-carboxylic Acid | |
| 摘要: 本文利用二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸(HDPPZC)作为有机配体在水热条件下制备了配合物[CoCl0.5(H2O)0.5(HDPPZC)2](PW12O40)0.5·3.5H2O (1)，利用X-射线单晶衍射、元素分析、紫外可见吸收光谱和差热分析对该化合物的结构进行了表征。单晶结构分析表明该晶体属于三斜晶系，P1空间群，晶胞系数a=1.036 0(2) nm，b=1.564 0(3) nm，c=1.656 0(3) nm，α=80.99(3)°，β=84.93(3)°，γ=85.44(3)°，V=2.6339(9) nm3，Z=1。配合物1是由零维离散结构通过氢键和π-π堆积形成的二维超分子结构。本文还研究了该化合物对罗丹明B的光催化降解性质。 | |
| 关键词: 钴(Ⅱ)化合物 晶体结构 光催化性质 | |
| 基金项目: 国家科学自然基金（No.61205040），江苏大学自然科学基金（No.09JDG001，11jdg104），江苏省自然科学基金（No.BK2012701，BK2011528）资助项目。 | |
| Abstract: [CoCl0.5(H2O)0.5(HDPPZC)2](PW12O40)0.5·3.5H2O (1) has been synthesized under hydrothermal conditions using HDPPZC (dipyrido[3,2-a∶2',3'-c]-phenazine-2-carboxylic acid) as a neutral organic ligand. Compound 1 has been characterized by single-crystal X-ray diffraction, elemental analysis, UV-Vis spectrum and thermogravimetric analysis (TGA). It crystallizes in triclinic, space group P1 with a=1.036 0(2) nm, b=1.564 0(3) nm, c=1.656 0(3) nm, α=80.99(3)°, β=84.93(3)°, γ=85.44(3)°, V=2.633 9(9) nm3, Z=1. Single-crystal X-ray diffraction analysis reveals that compounds 1 consists of a discrete dinuclear, linked by hydrogen bonding and π-π stacking interactions into 2D supramolecular framework. Furthermore, we studied the Rhodamine B (RhB) photodegration process by Compound 1 as the catalyst. CCDC: 968312. | |
| Keywords: cobalt(Ⅱ) compound crystal structure photocatalytic property | |
| 投稿时间：2013-05-14 修订日期：2013-10-09 | |
| 摘要点击次数: 2171 | |
| 全文下载次数: 2020 | |
| 施伟东,任傲,刘春波,白红叶,车广波,孙赫一,丛尧.含二吡啶[3,2-a∶2’,3’-c]并吩嗪-2-羧酸的Co(Ⅱ)配合物的合成、晶体结构及光催化性能研究[J].无机化学学报,2013,29(12):2649-2654. | |
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| Support information: 相关附件： file201312p2649 Supporting Information.pdf | |
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