| 铜N-杂环卡宾化合物的合成及其在有机合成中的应用 |
| Synthesis and Applications of Copper N-heterocyclic Carbene Complexes |
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| 摘要: N-杂环卡宾铜化合物具有简便易得，价廉低毒，性质稳定，结构类型多样并易于修饰等诸多优点，在很多领域具有重要的应用价值，因此铜的N-杂环卡宾化学在过去十几年中得到了快速发展。本文结合我们的工作，总结铜N-杂环卡宾化合物的合成方法、结构特点、转移卡宾配体用于合成其它金属卡宾化合物以及催化应用。 |
| 关键词: N-杂环卡宾|铜|合成|应用|催化 |
| 基金项目: 国家自然科学基金（No.20872129，21072170）资助项目。 |
| Abstract: The N-heterocyclic carbene (NHC) chemistry of copper has been flourishing in the past two decades. Cu-NHC complexes are of low cost and low toxicity which are easily available via various synthetic routes. Their structural diversity and ease of structural modification offer excellent opportunities for their versatile applications in the fields of catalysis, medicine, and materials. This review summarizes the synthetic routes to Cu-NHC complexes, structural features, carbene transfer reactivities and their applications in synthesis of other metal-NHC complexes, as well as their applications in catalysis. |
| Keywords: N-heterocyclic carbenes copper complexes synthesis applications catalysis |
| 投稿时间：2013-09-30 修订日期：2013-11-05 |
| 摘要点击次数: 2626 |
| 全文下载次数: 3308 |
| 刘波,陈万芝*.铜N-杂环卡宾化合物的合成及其在有机合成中的应用[J].无机化学学报,2014,30(1):20-36. |
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