| 一个由多元羧酸和含氮配体构成的二维Mn(Ⅱ)配合物的合成、表征和发光性能研究 | |
| One2D Mn(Ⅱ) Complex Constructed by Poly-Carboxylate and N-heterocyclic Ligands：Syntheses, Characterizations and Photoluminescent Properties | |
| 摘要: 本文采取水热合成方法，利用二元羧酸和含氮杂环配体作为混合配体设计合成了一个二维Mn(Ⅱ)配合物[Mn（mip）（NDC）]n（1）（mip=2-（3-methoxyphenyl）-1H-imidazo[4，5-f][1，10]phenanthroline，NDC=naphthalene-1，4-dicarboxylicacid），并对其进行元素分析、红外光谱分析、热失重分析、紫外-可见光谱分析和X-射线单晶衍射表征。配合物1属于单斜晶系，P21/n群，其晶胞参数如下：a=1.24580（7）nm，b=1.47450（9）nm，c=1.36544（8）nm，β=97.6440（1）°。在1中，金属锰(Ⅱ)与来自3个NDC配体的4个O原子和来自1个mip配体的2个N原子配位，形成扭曲的八面体构型。配合物1呈现二维（4，4）拓扑构型。热重分析表明配合物1的分解经历了两个阶段，并且该配合物的结构是比较稳定的。我们初步研究了配体和配合物1的荧光性能，结果表明配合物1可以做为潜在的发光材料。 | |
| 关键词: 晶体结构 热稳定性分析 荧光性能 | |
| 基金项目: 国家自然科学基金（No.20971019）；吉林省科学技术厅科研基金资助项目（No.20130522071JH）资助项目。 | |
| Abstract: One coordination complex constructed from dicarboxylate acid and N-heterocyclic ligand as mixed ligands, namely, [Mn(mip)(NDC)]n (1) (mip=2-(3-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, NDC= naphthalene-1,4-dicarboxylic acid) has been synthesized by hydrothermal reaction. Complex 1 was characterized by elemental analysis, infrared spectrum (IR), single crystal X-ray diffraction, UV-Vis spectrum, and thermogravimetric analysis (TGA). Complex 1 crystallizes in monoclinic, space group P21/n with a=1.24580(7) nm, b=1.47450(9) nm, c=1.36544(8) nm, β=97.6440(1)°. In1, the metal ions Mn(Ⅱ) act as distorted octahedral geometry, being surrounded by four carboxylate oxygen atoms from three NDC ligands and two donor nitrogen atoms from one mip molecule. Complex 1 shows 2D (4,4) sheet topology. TGanalysis shows two clear courses of weight loss, which corresponds to the decomposition of different ligands. The structure-related solid-state uorescence spectra of free ligands and complex 1 have been determined, and the result displays that complex 1 should be acted as potential luminescent material. CCDC: 919758. | |
| Keywords: crystal structures thermal stability fluorescence | |
| 投稿时间：2013-02-24 修订日期：2013-09-11 | |
| 摘要点击次数: 1469 | |
| 全文下载次数: 1585 | |
| 闫丽,孙明哲,任利,刘潇蒙,刘鹏,王毅慧.一个由多元羧酸和含氮配体构成的二维Mn(Ⅱ)配合物的合成、表征和发光性能研究[J].无机化学学报,2014,30(2):384-390. | |
| 查看全文 查看/发表评论 下载PDF阅读器 | |
| Support information: | |
|
| |
|
| |
|
| |