| 基于2-丙基-4，5-咪唑二甲酸的锰(Ⅱ)和铜(Ⅰ)配合物的合成、晶体结构及性质研究 |
| Synthesis, Crystal Structures, and Properties of Manganese(Ⅱ) and Copper(Ⅰ) with2-Propyl-4, 5-imidazoledicarboxylic Acid |
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| 摘要: 采用水热法合成了2个化合物{[Cu2(Hpimdc)(4，4’-bpy)]·H2O}n(1)和[Mn3(pimdc)2·6H2O]n(2)(H3pimdc=2-丙基-4，5-咪唑二甲酸，4，4’-bpy=4，4’-联吡啶)，并对2个化合物进行了红外、元素分析、晶体结构和热稳定性分析。晶体结构分析发现化合物1之中的H3pimdc和4，4’-bpy交替与铜(Ⅰ)配位形成一维链线性铜(Ⅰ)配合物。沿a轴和(100)面去观察，2个一维链分子通过游离水连接而形成1个“U”型拓扑结构。而化合物2通过2-丙基-4，5-咪唑二甲酸链与锰(Ⅱ)连接为三维的网状结构。沿b轴方向，三维结构中存在交替的左/右手螺旋状二维结构。 |
| 关键词: 2-丙基-4，5-咪唑二甲酸 晶体结构 热稳定性 螺旋链 |
| 基金项目: 广西壮族自治区教育厅广西高校科学技术研究项目(No.2013YB251);百色学院重点科研项目(No.2011KA02)资助项目。 |
| Abstract: Two complexes, namely {[Cu2(Hpimdc)(4,4'-bpy)]·H2O}n (1) and [Mn3(pimdc)2·6H2O]n (2)(H3pimdc=2-propyl-4,5-imidazoledicarboxylic acid) have been designed, synthensized and characterized (X-ray single crystal analysis, thermal analysis and IR Spectrum) based on the imidazole ligand. In complex 1, 4,4'-bpy acts as a secondary ligands. The complex 1 forms one-dimensional (1D) linear geometry via Hpimdc2- and 4,4'-bpy. Because of the free water, the complex 1 which connected two linear structures via hydrogen bonds, forms a U-type topology geometry (along a axis and (100) plane). The single-crystal structure of 2 reveals that the compound exhibits a 3Dframework, which is generated from 2Dright- and left-handed helical chains alternating with the other 2Dhelical chains along the b axis. CCDC: 793936, 1; 790206, 2. |
| Keywords: 2-propyl-4,5-imidazoledicarboxylic acid crystal structure thermal stability helical chain |
| 投稿时间：2013-08-02 修订日期：2014-04-04 |
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| 罗志荣,兰翠玲,隆金桥,赵金和,黎远成.基于2-丙基-4，5-咪唑二甲酸的锰(Ⅱ)和铜(Ⅰ)配合物的合成、晶体结构及性质研究[J].无机化学学报,2014,30(6):1373-1380. |
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