| 铁掺杂HTiNbO5纳米片及其催化环氧苯乙烷醇解的性能 | |
| Fe-Doped HTiNbO5 Nanosheets and Their Catalytic Performanc for Alcoholysis of Styrene Oxide | |
| 摘要: 通过先将层状HTiNbO5用四丁基氢氧化铵层离成单层纳米片，然后与铁溶胶重组，最后在不同温度（200~500℃）下焙烧，得到了一系列铁掺杂的HTiNbO5纳米片。研究结果表明，铁溶胶掺杂有利于提高催化剂的比表面积和酸性，所得催化剂在环氧苯乙烷的醇解反应中表现出很好的催化效果。其中，水解时间为1 h的铁溶胶与HTiNbO5纳米片重组且在400℃下焙烧后所得催化剂的催化效果最好，优于未掺杂和Fe3+直接絮凝的HTiNbO5纳米片。 | |
| 关键词: 多相催化 纳米技术 层状化合物 铁掺杂HTiNbO5 纳米片 Fe 醇解 环氧苯乙烷 | |
| 基金项目: 国家自然科学基金（No.21073084），国家基础科学人才培养基金（No.J1103310），江苏省自然科学基金（No.BK2011438），高等学校博士学科点专项科研基金资助课题（No.20130091110010），国家重点基础研究发展计划（No.2009CB623504）资助项。 | |
| Abstract: Iron-doped HTiNbO5 nanosheets catalysts were prepared via the assembly of exfoliated-HTiNbO5 nanosheets and iron sols followed by calcination at a temperature range of 200~500℃. Doping by Fe sols is beneficial to the enhancement of surface area and acidity of the catalysts. The title catalysts exhibit excellent catalytic performance in the alcoholysis of styrene epoxide with different alcohols. Compared with undoped HTiNbO5 nanosheets, the Fe ions doped catalyst obtained through the Fe sols with a hydrolysis time of 1 h and a calcination temperature of 400℃ shows a higher catalytic performance. | |
| Keywords: heterogeneous catalysis nanotechnology layered compounds Fe-doped HTiNbO5 nanosheets iron alcoholysis styrene epoxide | |
| 投稿时间：2013-12-26 修订日期：2014-03-14 | |
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| 张丽宏,胡晨晖,张俊峰,程立媛,侯文华,陈静.铁掺杂HTiNbO5纳米片及其催化环氧苯乙烷醇解的性能[J].无机化学学报,2014,30(8):1813-1820. | |
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