| 微相分离理论在金属有机框架化合物中的应用：基于Ni（Ⅱ）和蒽醌四羧酸（H4AQTC）的配位聚合物的研究 |
| Application of Micro-phase Separation Theory in MOFs：a Case Study of Coordination Polymers Based on Ni(Ⅱ) and H4AQTC Ligand |
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| 摘要: 通过使用不同尺寸的辅配体，我们合成了一系列以二价镍为金属离子，蒽醌四羧酸为主配体的金属有机框架化合物（1~5）。根据微相分离理论，通过选用不同尺寸的辅配体来调节聚合物的疏水体积比，我们得到具有不同结构的一系列配位聚合物。实验结果表明，化合物1和2表现为简单的二维层状结构，化合物3和4具有准三维结构，化合物5则具有三重穿插的二维结构。实验结果与微相分离理论所预测的结果相吻合。 |
| 关键词: 微相分离理论 晶体结构 金属有机框架 蒽醌四羧酸 |
| 基金项目: 国家自然科学基金（No.21021062和91122031）江苏省自然科学基金（No.BK2011550）资助项目 |
| Abstract: By using secondary ligands of different sizes, we prepared a series of MOFs (complexes 1~5) based on Ni(Ⅱ) as metal iron and anthraquinone-1,4,5,8-tetracarboxylic acid (H4AQTC) as the main ligand. According to Micro-phase Separation Theory, these coordination polymers are hypothesized to show different structures because of their different hydrophobic volume ratio, which was actually adjusted by the secondary ligands. Our results showed that complexes 1 and 2 revealed simple 2-dimensional layered structure, while complexes 3 and 4 produced quasi-3-dimensional structure. Complex 5 possessed a 2-dimensinal structure with 3-fold interpenetrating pattern. Therefore in our cases, the experimental data is consistent with the prediction of Micro-phase Separation Theory. CCDC: 966901, 1; 966902, 2; 966903, 3; 966904, 4; 966905, 5. |
| Keywords: micro-phase separation theory crystal structure metal-organic frameworks(MOFs) anthraquinone-1,4,5,8-tetracarboxylic acid |
| 投稿时间：2014-03-12 修订日期：2014-05-04 |
| 摘要点击次数: 1709 |
| 全文下载次数: 1899 |
| 丁刘镠,陈琪,盛小利,王冬妮,芦昌盛.微相分离理论在金属有机框架化合物中的应用：基于Ni（Ⅱ）和蒽醌四羧酸（H4AQTC）的配位聚合物的研究[J].无机化学学报,2014,30(9):1985-1993. |
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