| 芳基取代茚基钌羰基化合物的合成及晶体结构 | |
| Ruthenium Carbonyl Complexes Involving Aryl-Substituted Indenyl Ligands: Syntheses and Structures | |
| 摘要: 配体C9H7R(R=Ph(1),4-tolyl(2),4-chlorophenyl(3),4-methoxyphenyl(1),2-thienyl(5))分别与Ru3(CO)12在甲苯或二甲苯中加热回流,得到了5个双核配合物[(η5-C9H6R)Ru(CO)]2(μ-CO)2(R=Ph(6),4-tolyl(7),4-chlorophenyl(8),4-methoxyphenyl(9),2-thienyl(10))。通过元素分析、红外光谱、核磁共振氢谱对配合物的结构进行了表征,并用X-射线单晶衍射法测定了配合物6,7和10的结构。 | |
| 关键词: 茚基 羰基钌 X-射线衍射 结构 | |
| 基金项目: 国家自然科学基金(No.21372061),河北省自然科学基金(No.B2013205025,B2014205018)和河北师范大学重点基金(No.L2012Z02)资助项目。 | |
| Abstract: Reactions of aryl-substituted indenyl ligands (R=Ph (1), 4-tolyl (2), 4-chlorophenyl (3), 4-methoxy-phenyl (4), 2-thienyl (5)) with Ru3(CO)12 in refluxing toluene or xylene gave the responding dinuclear metal carbonyl complexes [(η5-C9H6R)Ru(CO)]2(μ-CO)2 (R=Ph (6), 4-tolyl (7), 4-chlorophenyl (8), 4-methoxyphenyl (9), 2-thienyl (10)), respectively. These complexes have been characterized by elemental analysis, IR, and 1H NMR spectroscopy. The molecular structures of 6, 7 and 10 were determined by X-ray diffraction analysis. | |
| Keywords: indenyl ruthenium carbonyl X-ray diffraction structure | |
| 投稿时间：2015-01-09 修订日期：2015-02-06 | |
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| 马志宏,刘英春,李素贞,韩占刚,郑学忠,林进.芳基取代茚基钌羰基化合物的合成及晶体结构[J].无机化学学报,2015,31(5):1049-1054. | |
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