| 一系列由柔性N,N'-双(3-吡啶甲基)胺构筑的螺旋配合物的合成、结构和性质 | |
| Syntheses, Crystal Structures and Properties of a Series of Helical Complexes Constructed by Flexible N,N'-Bis(3-pyridylmethyl)amine | |
| 摘要: 合成和表征了5个螺旋配位聚合物{[Cu(Hbpma)(H2O)4]2(SO4)3·3.5H2O}n (1)、{[Ni(Hbpma)(H2O)4]4(SO4)6·10.75H2O}n (2)、{[Mn(Hbpma)(H2O)4](SO4)1.5·3H2O}n (3)、{[Zn(Hbpma)(H2O)4]4(SO4)6·4H2O·4CH3OH}n (4)和{[Cu(Hbpma)2(H2O)2](SO4)2·9H2O}n (5),其中bpma代表N,N'-双(3-吡啶甲基)胺。晶体结构分析表明配合物1~4为一维链状结构,配合物5为二维层状结构,其中金属离子由质子化的bpma配体桥连。值得注意的是,采取反-反式构象的柔性bpma配体使得配合物1和2为假螺旋链结构,配合物3和4为螺旋链结构,配合物5为螺旋层结构。同时研究了配合物的磁性和热稳定性。 | |
| 关键词: 金属配合物 N,N'-双(3-吡啶甲基)胺 螺旋结构 磁性 热稳定性 | |
| 基金项目: | |
| Abstract: Five helical coordination polymers {[Cu(Hbpma)(H2O)4]2(SO4)3·3.5H2O}n (1), {[Ni(Hbpma)(H2O)4]4(SO4)6·10.75H2O}n (2), {[Mn(Hbpma)(H2O)4](SO4)1.5·3H2O}n (3), {[Zn(Hbpma)(H2O)4]4(SO4)6·4H2O·4CH3OH}n (4) and {[Cu(Hbpma)2(H2O)2](SO4)2·9H2O}n (5) (bpma=N,N'-bis(3-pyridylmethyl)amine) were synthesized and structurally char-acterized. The single-crystal X-ray analyses indicate that complexes 1~4 crystallize in the one-dimensional chain structures and complex 5 shows the two-dimensional layer structure, in which the metal ions are bridged by the protonated bpma ligands. It is noted that the flexible bpma ligands with the trans-trans conformation lead to the pseudo-helical chains for complexes 1~2, the helical chains for complexes 3~4 and a helical layer for complex 5. The magnetic properties and the thermal behavior are investigated. CCDC: 966929, 1; 966932, 2; 966930, 3; 966931, 4; 1054736, 5. | |
| Keywords: metal complex N,N'-bis(3-pyridylmethyl)amine helical structure magnetic property thermal behavior | |
| 投稿时间：2015-04-13 修订日期：2015-05-28 | |
| 摘要点击次数: 1402 | |
| 全文下载次数: 1497 | |
| 岳翠敏,高东昭,王修光.一系列由柔性N,N'-双(3-吡啶甲基)胺构筑的螺旋配合物的合成、结构和性质[J].无机化学学报,2015,31(8):1609-1618. | |
| 查看全文 查看/发表评论 下载PDF阅读器 | |
| Support information: 相关附件： file150224_SI.docx | |
|
| |
|
| |
|
| |