水稳定的镁掺杂ZnO量子点:一锅法合成及细胞成像应用 |
Water-Stable Magnesium-Doped ZnO Quantum Dots: One-Pot Synthesis and Cell Labeling Applications |
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摘要: 一锅法合成了镁掺杂的ZnO量子点,利用APTES对其进行表面包覆,并采用XRD、TEM、UV-Vis、PL和FTIR等对材料进行了表征。结果表明镁掺杂能明显增强荧光发光强度,在合适的掺杂浓度(30%)下其量子产率由11%增加到33%。通过APTES的表面包覆使镁掺杂的ZnO量子点具有良好的水溶性和荧光稳定性,可用于MCF-7细胞成像研究。 |
关键词: ZnO量子点 镁掺杂 APTES包覆 水稳定性 |
基金项目: 黑龙江省教育厅科学技术研究基金(No.12541910)资助项目。 |
Abstract: A one-pot method was developed for synthesizing Magnesium-doped ZnO quantum dots (QDs) capped with (3-aminopropyl)triethoxysilane (APTES). The as-prepared quantum dots were characterized by XRD, TEM, UV-Vis, FL (fluorescent spectroscopy) and FTIR. The results show that the Mg-doped quantum dots exhibit greatly enhanced luminescent property and their quantum yield is increased from 11% for un-doped ZnO QDs to 33% for Mg-doped ZnO QDs at Mg-doping content of 30%. In addition, aqueous-stability is achieved by capping the Mg-doped ZnO QDs with APTES. The obtained APTES-capped Mg-doped ZnO QDs exhibit excellent water stability and retain visible emissions. The APTES-capped Mg-doped ZnO QDs demonstrate promising applications in MCF-7 cell labeling. |
Keywords: ZnO quantum dots magnesium-doped APTES-capped aqueous-stability |
投稿时间:2015-05-04 修订日期:2015-07-01 |
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张立平,吴山,刘丹,万永刚,刘道森.水稳定的镁掺杂ZnO量子点:一锅法合成及细胞成像应用[J].无机化学学报,2015,31(8):1644-1650. |
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Support information: 相关附件: file150278Supporting Information.pdf |
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