| 一些二茂铁苯基亚胺化合物的合成与表征 |
| Synthesis and Characterization of Some Ferrocenylphenylimine Compounds |
| 作者 | 单位 | E-mail | | Ikhile Monisola I | Department of Applied Chemistry, University of Johannesburg, Doornfontein Campus, P. O. Box 17011, Doornfontein 2028, Johannesburg, South Africa | mikhile@uj.ac.za | | Ngila J Catherine | Department of Applied Chemistry, University of Johannesburg, Doornfontein Campus, P. O. Box 17011, Doornfontein 2028, Johannesburg, South Africa | jcngila@uj.ac.za |
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| 摘要: 通过回流对应的二茂铁苯胺和芳香醛的混合物的同样路径合成了一系列新颖的二茂铁苯基亚胺化合物(5~12)。当暴露于空气时化合物5~12稳定,不发生任何分解。所有化合物均用1H、13C NMR,MS,IR,UV-Vis和元素分析表征。还报导了化合物N-(3-bromo-2-hydroxylbenzylidene)-4-ferrocenylimine(10)的单晶结构,其结晶属单斜晶系P21/c空间群。 |
| 关键词: 二茂铁 合成 表征 亚胺 X-射线衍射 |
| 基金项目: Supported by Faculty of Science, University of Johannesburg, South Africa. |
| Abstract: A novel series of ferrocenylimine compounds (5~12) were synthesized via the same route by refluxing a mixture of corresponding ferrocenylaniline with aromatic aldehyde. Compounds 5~12 were air stable without any decomposition when exposed to air. The compounds were all characterized by 1H and 13C NMR spectroscopy, mass spectrometry, IR, UV-Visible and elemental analysis. The single crystal structure of compound 10 was also reported, which revealed that compound 10 crystallized in monoclinic system with P21/c space group. CCDC: 1010246, 10. |
| Keywords: ferrocene synthesis characterization imine X-ray diffraction |
| 投稿时间：2015-06-23 修订日期：2015-08-31 |
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| Ikhile Monisola I,Ngila J Catherine.一些二茂铁苯基亚胺化合物的合成与表征[J].无机化学学报,2015,31(10):2079-2088. |
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