| 4d-4f异金属配位聚合物的合成、结构和荧光性质 |
| Syntheses, Structures and Photoluminescent Properties of Three 4d-4f Heterometallic Coordination Polymers |
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| 摘要: 在水热反应条件下成功地合成了3个4d-4f异金属化合物{[LnAg2(QA)4(H2O)5](ClO4)}n(Ln=Nd(1),Tb(2),Eu(3);HQA=3-喹啉羧酸)。用单晶衍射分析,元素分析和粉末衍射分析对晶体结构进行了表征。化合物1~3同构,在bc平面形成二维层结构,抗衡离子ClO4-与二维层通过氢键作用形成三维超分子结构。研究了配合物2和3的荧光性质。 |
| 关键词: 异金属 配位聚合物 水热合成 原位脱羧 荧光性质 |
| 基金项目: 山西师范大学博士科研启动金(No.833114)资助项目。 |
| Abstract: Three 4d-4f heterometallic coordination compounds, namely, {[LnAg2(QA)4(H2O)5](ClO4)}n(Ln=Nd(1), Tb(2), Eu(3); HQA=3-quinolinecarboxylate acid), were successfully synthesized under hydrothermal conditions.Compounds 1~3 are isostructural and feature 2D layer structures on bc plane, which are further connected by the counter anions ClO4- by hydrogen bonds into 3D supermolecular structure.All these compounds are characterized by single-crystal X-ray diffraction, elemental analyses(EA) and powder X-ray diffraction(PXRD).Furthermore, the thermal stabilities and fluorescent properties of the selected compounds have been investigated.CCDC:1038767, 1; 1039837, 2; 1038768, 3. |
| Keywords: heterometallic coordination polymer hydrothermal synthesis in situ decarboxylation luminescent properties |
| 投稿时间：2015-11-16 修订日期：2016-01-21 |
| 摘要点击次数: 1998 |
| 全文下载次数: 1809 |
| 李彩红,张瑞凤.4d-4f异金属配位聚合物的合成、结构和荧光性质[J].无机化学学报,2016,32(4):713-719. |
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