| 基于3,5-双(4-吡啶基)-吡啶的两个钴(Ⅱ)配合物的合成与晶体结构 |
| Syntheses and Crystal Structures of Two Cobalt(Ⅱ) Compounds Based on 3,5-Bis(4-pyridyl)-pyridine |
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| 摘要: 用3,5-双(4-吡啶基)-吡啶(BPYPY)分别与反式-1,4-环己烷二甲酸(trans-H2chdc)和4,4'-联苯醚二甲酸(H2oba)组成混合配体,用温和的溶剂热法与Co(NO3)2·6H2O合成了2个配合物[Co(BPYPY)2(H2O)4]·(trans-chdc)·4H2O (1)和{[Co(BPYPY)(H2O)4]·(oba)}n(2),利用X射线单晶衍射、元素分析对它们进行了表征。结果显示,配合物1为单核结构,属于单斜晶系,P21/n空间群;配位聚合物2是一维链通过O-H…O氢键形成的三维超分子结构,属于正交晶系,Pccn空间群。 |
| 关键词: 晶体结构 合成 钴(Ⅱ)配合物 含氮配体 |
| 基金项目: 国家自然科学基金(No.21371092)、安徽高校省级自然科学研究重点项目(KJ2015A203)、安徽省自然科学基金(1408085MB40)和宿州学院自旋电子与纳米材料安徽省重点实验室开放课题(2014YKF51)资助 |
| Abstract: Two compounds[Co(BPYPY)2(H2O)4]·(trans-chdc)·4H2O (1) and {[Co(BPYPY)(H2O)4]·(oba)}n (2) were synthesized by mild hydrothermal method using two mixed-ligands consisting of 3,5-bis(4-pyridyl)-pyridine (BPYPY), trans-1,4'-cyclohexanedicarboxylic acid (trans-H2chdc), 4,4'-oxydibenzoic acid (H2oba) and Co(NO3)2·6H2O. The complexes were characterized by elemental analysis and their crystal structures were determined by single-crystal X-ray diffraction. Structural analyses show that compound 1 is mononuclear complex, and crystallizes in the monoclinic system, space group P21/n; compound 2 is a 1D chain and further extended via O-H…O interaction to generate infinite 3D supramolecular structure, and crystallizes in the orthorhombic system, space group Pccn. |
| Keywords: crystal structure synthesis Co(Ⅱ) compound N-containing ligands |
| 投稿时间：2015-11-23 修订日期：2016-01-30 |
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| 张春丽,王红艳,郑和根.基于3,5-双(4-吡啶基)-吡啶的两个钴(Ⅱ)配合物的合成与晶体结构[J].无机化学学报,2016,32(5):859-863. |
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