| 两种1,2,3-三唑衍生物的配合物合成策略:晶体结构和表面分析 |
| A Synthetic Strategy for Two Complexes with 1, 2, 3-Triazole Derivatives: Crystal Structures and Hirshfeld Surface Analysis |
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| 摘要: 在不同反应条件下反应得到了两种1，2，3-三唑衍生物的配合物[Co（H2O）6][Co（L1）3]2·4H2O（1）和Cu（L2）2（2）（HL1=5-methyl-1-phenyl-1H-1，2，3-triazole-4-carboxylic acid；HL2=1-（4-iodophenyl）-5-methyl-1H-1，2，3-triazole-4-carboxylic acid）。通过X射线单晶衍射和红外光谱确定了晶体结构，同时对配合物1和2进行了表面作用分析（Hirshfeld surface analysis），在二维指纹图谱中可以清楚的看到配合物中的主要分子间作用。 |
| 关键词: 1H-1,2,3-三唑衍生物 晶体结构 表面分析 二维指纹区 |
| 基金项目: |
| Abstract: Two new complexes [Co(H2O)6][Co(L1)3]2·4H2O (1) and Cu(L2)2 (2) were synthesized by 1H-1,2,3-triazole acid derivatives under various reaction conditions(HL1=5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid; HL2=1-(4-iodophenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylic acid). The crystal structures have been established by single-crystal X-ray diffraction, and characterized by FTIR. Hirshfeld surface analysis for complexes 1 and 2 indicate that the 2D fingerprint plots obviously show the main intermolecular interactions in both complexes. |
| Keywords: 1H-1,2,3-triazole acid derivatives crystal structure Hirshfeld surface analysis 2D fingerprint plots |
| 投稿时间：2015-12-12 修订日期：2016-05-02 |
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| 冯超,张舵,周士艳,陈金梅,左泽浩,赵红.两种1,2,3-三唑衍生物的配合物合成策略:晶体结构和表面分析[J].无机化学学报,2016,32(7):1215-1222. |
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