| Ru/Ce(OH)CO3纳米复合材料催化氨硼烷水解产氢 |
| Hydrolysis of Ammonia Borane by Ru/Ce(OH)CO3 Nanocomposites for Hydrogen Production |
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| 摘要: 采用一种简单的方法快速合成了Ru/Ce（OH）CO3纳米复合材料。基于TG，XRD，TEM，EDX，XPS和ICP等方法详细表征了所制备的催化剂，并用于催化氨硼烷水解制氢。表征结果表明尺寸大约为4.8 nm的Ru纳米粒子高度分散在Ce（OH）CO3纳米棒上。该催化剂对于氨硼烷水解制氢表现出优异的催化性能，在室温下其转化频率（TOF）达到389.6 molH2·molRu-1·min-1。而且该催化剂循环使用11次之后依然能够对氨硼烷催化产氢保持很高的活性。 |
| 关键词: 能源材料 氨硼烷 稀土 催化水解 制氢 |
| 基金项目: 国家自然科学基金（No.21463012）和江西省自然科学基金（No.2016BAB203087）资助项目。 |
| Abstract: A facile method for fabrication of Ru/Ce(OH)CO3 nanocomposites (NCs) under mild conditions was reported. The as-synthesized catalysts were characterized by TG, XRD, TEM, EDX, XPS, ICP, and used for H2 production from hydrolysis of ammonia borane (AB). All the characterized results exhibit that Ru nanoparticles (NPs) around 4.8 nm are highly dispersed on Ce(OH)CO3 nanorods. The as-synthesized Ru/Ce(OH)CO3 NCs show a high catalytic activity for hydrogen generation from the aqueous of ammonia borane complex with a turnover frequency (TOF) of 389.6 molH2·molRu-1·min-1 at room temperature, being higher than that of most reported metal-based catalysts. Especially, the catalyst can keep a superior activity for hydrolysis of AB even after eleven times of recycle. |
| Keywords: energy storage materials ammonia borane rare earth oxide catalytic hydrolysis hydrogen generation |
| 投稿时间：2016-03-30 修订日期：2016-09-05 |
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| 陈健民,卢章辉,熊丽华.Ru/Ce(OH)CO3纳米复合材料催化氨硼烷水解产氢[J].无机化学学报,2016,32(10):1816-1824. |
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| Support information: 相关附件： file160187_Supplementary data.doc |
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