| N-对甲苯磺酰-5-氨基间苯二甲酸构筑的一维配位聚合物的合成、晶体结构和荧光性质 |
| Syntheses, Crystal Structures and Fluorescent Properties of One-Dimensional Coordination Polymers with N-p-Tolylsulfonyl-5-aminoisophthalic Acid |
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| 摘要: 采用普通溶液法和水热法分别合成了2个金属-有机配位聚合物：{[Cu（Ts-5-AIPA）（phen）（H2O）]·H2O}n（1）和[Cd（Ts-5-AIPA）（phen）]n（2）（Ts-5-AIPA=N-对甲苯磺酰-5-氨基间苯二甲酸根，phen=菲咯啉），并用红外光谱、热重和X射线单晶衍射对配合物的结构进行了表征。结果表明：2个配合物均为单斜晶系，配合物1为P21/c空间群，配合物2为C2/c空间群；2个配合物均为一维链状结构，再通过氢键和π-π堆积作用形成三维超分子结构。另外，还研究了2个配位聚合物的荧光性质。 |
| 关键词: 配位聚合物|N-对甲苯磺酰-5-氨基间苯二甲酸|晶体结构|荧光 |
| 基金项目: 福建省教育厅基金（No.JA14261）和国家大学生创新创业训练（No.201610399007）资助项目。 |
| Abstract: Two metal-organic coordination polymers, {[Cu(Ts-5-AIPA)(phen)(H2O)]·H2O}n (1) and [Cd(Ts-5-AIPA)(phen)]n (2) (Ts-5-AIPA=N-p-tolylsulfonyl-5-aminoisophthalic acid radical, phen=phenanthroline), were synthesized using common solution method and hydrothermally method, respectively. Their crystal structures were determined by IR, TG and single-crystal X-ray diffraction. Two complexes crystalize in monoclinic system, space group P21/c for complex 1 and C2/c for complex 2. They are one-dimensional chain structure, and further extended into a three-dimensional supramolecular structure through hydrogen bonds and π-π interactions. In addition, fluorescent properties of two complexes were investigated. CCDC:839135, 1; 1472441, 2. |
| Keywords: coordination polymer|N-p-tolylsulfonyl-5-aminoisophthalic acid|crystal structure|fluorescent |
| 投稿时间：2016-07-08 修订日期：2016-11-02 |
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| 黄妙龄,吴文士,陈婉贞.N-对甲苯磺酰-5-氨基间苯二甲酸构筑的一维配位聚合物的合成、晶体结构和荧光性质[J].无机化学学报,2017,33(1):66-72. |
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