| 结晶性的多孔高分子-金属配合物的最新研究进展——合成、表征和性质 | |
| Recent Progress of Crystalline and Porous Polymer-Metal Coordination Complexes: Synthesis, Characterization and Properties | |
| 摘要: 由于高分子具有尺寸长短不一、柔性等特点，很难通过普通方法合成具有结晶性和多孔性的高分子材料。而高分子金属配合物材料不仅继承了高分子材料的传统性质，同时也可以获得配合物的优点，比如高结晶性和多孔性。本文系统总结了合成结晶性的多孔高分子配合物材料的方法，包括光诱导聚合法、配位自主装法、分步合成法以及后修饰法。同时介绍了它们的表征方法以及潜在应用领域，并讨论了该领域研究中存在的各种机遇与挑战。 | |
| 关键词: 结晶性 多孔性 高分子金属配合物 后修饰 自组装 | |
| 基金项目: 国家自然科学基金（No.21601093）和中国青年千人计划资助项目。 | |
| Abstract: It is always a great challenge to synthesize crystalline and porous polymer materials due to the random configuration and flexibility of polymers. However, polymer-metal coordination complexes (PMCCs) can exhibit high porosity and crystallinity because PMCCs possess not only the properties of polymers such as flexibility and good processability but also the properties of coordination complexes such as high crystallinity and porosity. Herein, this review article summarizes the methods how to construct porous and crystalline PMCCs including photo-induced polymerization method, coordination bond induced self-assembly method, two-step synthesis method and post-synthetic modification method. Finally, we discusse the characterization methods and the potential applications of PMCCs, and list the challenges and chances in the field. | |
| Keywords: crystallinity porosity polymer-metal coordination complexes post-synthetic modification self-assembly 0 Introduction | |
| 投稿时间：2017-08-07 修订日期：2017-08-22 | |
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| 喻琪,陈瑶,张振杰,程鹏.结晶性的多孔高分子-金属配合物的最新研究进展——合成、表征和性质[J].无机化学学报,2017,33(11):1991-2004. | |
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