Ho3+/Yb3+共掺ZnO-Al2O3-GeO2-SiO2玻璃陶瓷的制备和上转换发光性质
Preparation and Up-Conversion Luminescence Properties of Ho3+/Yb3+ Co-doped ZnO-Al2O3-GeO2-SiO2 Glass Ceramics
作者单位E-mail
李明月 长春理工大学化学与环境工程学院, 长春 130022  
邹翔宇 长春理工大学化学与环境工程学院, 长春 130022  
张洪波 长春理工大学化学与环境工程学院, 长春 130022  
邵晶 长春理工大学化学与环境工程学院, 长春 130022 shaojing7079@163.com 
苏春辉 长春理工大学化学与环境工程学院, 长春 130022
长春师范大学, 长春 130051 
sch@cust.edu.cn 
摘要: 综合ZnO-Al2O3-SiO2系和锗酸盐玻璃陶瓷的优点,采用熔融-晶化法首次制备了Ho3+/Yb3+共掺以ZnAl2O4为主晶相的ZnO-Al2O3-GeO2-SiO2系玻璃陶瓷。因[GeO4]四面体和[SiO4]四面体都是玻璃网络形成体,讨论了GeO2取代SiO2对玻璃陶瓷样品硬度及发光性能的影响,最终确定GeO2的取代量为10.55%(w/w)时,玻璃陶瓷综合性能最佳。在980 nm泵浦光的激发下,发现强的绿色(546 nm)和弱的红色(650 nm)上转换发光,并研究了不同Ho3+/Yb3+掺杂比对样品上转换发光的影响,最终结果表明当Ho3+/Yb3+掺杂比为1:11(n/n)时样品荧光强度最强,在绿色上转换发光材料方面具有潜在的应用。
关键词: 玻璃陶瓷  ZnAl2O4  Ho3+/Yb3+共掺  上转换发光  硬度
基金项目: 国家863项目(No.2011AA030204)和吉林省科技厅重点项目(No.20150204051GX、20160204027GX)资助。
Abstract: Combining the advantages of ZnO-Al2O3-SiO2 system and germinate glass ceramics, Ho3+/Yb3+ co-doped ZnO-Al2O3-GeO2-SiO2 glass ceramics containing ZnAl2O4 crystalline phase were successfully prepared by melt-crystallization technique for the first time. Because the tetrahedral[GeO4] and tetrahedral[SiO4] are glass network skeleton, Subsequently, the influence of GeO2 instead of SiO2 on the hardness and up-conversion luminescence properties of glass ceramic samples is discussed here. Ultimately, when the quantity of GeO2 instead of SiO2 was 10.55%(w/w), comprehensive performance of the glass ceramic samples were optimum. Under the 980 nm pump light excitation, a strong green emission (546 nm) and a weak red emission (650 nm) are observed. The effect of different doped ratios of Ho3+/Yb3+ on the up-conversion luminescence of samples was studied. The experimental results indicated that the luminescence intensity reaches a maximum when the doped ratios of Ho3+:Yb3+ is 1:11 and the samples have potential application on green up-conversion luminescence material.
Keywords: glass ceramic  ZnAl2O4  Ho3+/Yb3+ co-doped  up-conversion luminescence  hardness
投稿时间:2017-05-25 修订日期:2017-10-28
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李明月,邹翔宇,张洪波,邵晶,苏春辉.Ho3+/Yb3+共掺ZnO-Al2O3-GeO2-SiO2玻璃陶瓷的制备和上转换发光性质[J].无机化学学报,2018,34(1):105-111.
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