配合物(BenzMeIm)2[PtCl4]的合成与表征
Synthesis and Characterization of Complex (BenzMeIm)2[PtCl4]
作者单位E-mail
Mohamad Ali Hikmat Department of Chemistry, College of Education, University of Salahaddin, Erbil, Iraq hikmatmohamad@yahoo.com 
Mahmoud Jamal Azheen Department of Chemistry, College of Education, University of Salahaddin, Erbil, Iraq  
Gerber Thomas Department of Chemistry, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa  
Hosten Eric Department of Chemistry, Nelson Mandela Metropolitan University, Port Elizabeth, South Africa  
摘要: 通过离子液体氯化1-苄基-3-甲基咪唑(BenzMeIm-Cl)与PtCl2的反应,合成了配合物(BenzMeIm)2[PtCl4],并用元素分析、红外光谱、紫外-可见光谱、1H NMR、13C NMR和单晶X射线衍射对其进行了表征。单晶X射线分析表明,配合物结构属于P21/c空间群,晶胞参数和结构解析参数为:a=0.981 80(5)nm,b=0.861 47(3)nm,c=0.144 332(7)nm,β=92.480(2)°,V=121.96(1)nm3R1=0.014 4,wR2=0.038 8。
关键词: 氯化1-苄基-3-甲基咪唑    配合物  晶体结构
基金项目: 
Abstract: A complex of (BenzMeIm)2[PtCl4] was prepared by the reaction of 1-benzyl-3-methylimidazolium chloride (BenzMeIm-Cl) with PtCl2. The structure of the complex was characterized by single crystal X-ray analysis, and it crystallizes in the monoclinic P21/c space group, with a=0.981 80(5) nm, b=0.861 47(3) nm, c=0.144 332(7) nm, β=92.480(2)°, V=121.96(1) nm3, R1=0.014 4, wR2=0.038 8.
Keywords: 1-benzyl-3-methylimidazolium chloride  Pt(Ⅱ)  complex  crystal structure
投稿时间:2017-08-24 修订日期:2018-01-25
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Mohamad Ali Hikmat,Mahmoud Jamal Azheen,Gerber Thomas,Hosten Eric.配合物(BenzMeIm)2[PtCl4]的合成与表征[J].无机化学学报,2018,34(4):728-732.
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