锥形构象含氟杯芳烃衍生物对铜离子的高选择性识别
Highly Selective Recognition to Cu2' Based on Fluorinated Calix[4]arene Derivatives in Cone Conformation
作者单位E-mail
齐琪 宁波大学材料科学与化学工程学院, 浙江省光电探测材料及器件重点实验室, 宁波 315211  
李星 宁波大学材料科学与化学工程学院, 浙江省光电探测材料及器件重点实验室, 宁波 315211 lixing@nbu.edu.cn,lix905@126.com 
摘要: 合成了具有锥形构象的含氟功能基团的杯芳烃衍生物1~3,并用单晶X射线衍射和核磁共振证实了其锥形构象。在混合溶剂中,研究了杯芳烃衍生物1~3对多种金属离子的识别行为。测试了化合物1~3的紫外-可见吸收光谱和荧光发射光谱,结果显示铜离子对化合物1~3具有明显的荧光猝灭特性,而其它金属离子(如Na',K',Cs',Mg2',Ca2',Ba2',Fe3',Cd2',Mn2',Co2',Ni2',Zn2')对化合物1~3的紫外-可见吸收光谱和荧光发射强度无显著的影响,表明化合物1~3对铜离子的识别具有高选择性。
关键词: 杯[4]芳烃  识别  选择性  含氟衍生物
基金项目: 国家自然科学基金(No.21571110)、浙江省自然科学基金(No.LY18B010003)和宁波大学王宽诚幸福基金资助项目
Abstract: The fluorine derivatives of calix[4]arene, C64H52F12O4 (1), C60H52F4O4 (2), C68H48F24O4 (3), were synthesized, and their cone conformations were proved by single crystal X-ray diffraction and 1H NMR spectroscopy. Their recognition behaviors were evaluated towards a variety of metal ions in mixed solvent. The UV-Vis absorption and fluorescence spectroscopy were measured and confirmed that copper ions resulted in fluorescence quenching of compounds 1~3, while other ions such as Na', K', Cs', Mg2', Ca2', Ba2', Fe3', Cd2', Mn2', Co2', Ni2', Zn2' exerted hardly significant impact on the UV-Vis absorption and fluorescence intensity of 1~3, exhibiting high selectivity of compounds 1~3 to copper ions.
Keywords: calix[4]arene  recognition  selectivity  fluorinated derivatives
投稿时间:2019-03-01 修订日期:2019-05-13
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齐琪,李星.锥形构象含氟杯芳烃衍生物对铜离子的高选择性识别[J].无机化学学报,2019,35(7):1301-1311.
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