| 单分散共价有机框架纳米颗粒的室温快速制备 |
| Rapid Synthesis of Monodisperse Covalent Organic Frameworks Nano-Particles at Ambient Temperature |
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| 摘要: 以稀土金属三氟甲磺酸盐作为新型的共价有机框架（COF）合成催化剂，成功制备了4种不同结构的COF （COF-42、TPBDMTP、RT-COF-1、COF-LZU1）的单分散纳米级颗粒，并通过对反应条件的系统性调控，实现200~900 nm范围内精确控制COF的粒径。X射线衍射表征证明了产物良好的结晶性。此外，相较于传统的水热合成，该方法可在室温常压条件下操作，并且在0.5 h内快速得到产物。 |
| 关键词: 共价有机框架 金属三氟甲磺酸盐 室温合成 单分散 纳米颗粒 |
| 基金项目: 国家自然科学基金项目（No.22025106，91545205，91622103，21971199，82002879）、国家重点研发计划项目（No.2018YFA0704000）、武汉大学创新团队（No.2042017kf0232）和中国博士后科学基金（No.2021M692475，2021T140524，XJ2021037）资助。 |
| Abstract: Herein, the rare earth metal trifluoromethanesulfonate salts can function as new types of catalyst for the synthesis of covalent organic frameworks (COF), to accelerate the synthesis of four different types of COF (COF-42, TPB-DMTP, RT-COF-1, COF-LZU1) under ambient conditions and form desirable monodisperse COF nano-particles. Through the systematic optimization of the reaction conditions, the size of the COF particle was precisely controlled in a range of 200~900 nm. X-ray diffraction analysis showed that the resulting COF nano-particle exhibited good crystallinity. In addition, compared with the traditional method usually requiring high-temperature (120℃), this method is suitable for COF production at ambient temperature and pressure within half an hour. |
| Keywords: covalent organic frameworks metal trifluoromethanesulfonate ambient temperature synthesis monodisperse nano-particles |
| 投稿时间：2021-08-12 修订日期：2021-09-08 |
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| 伍延如真,易乐智,张亮,邓鹤翔.单分散共价有机框架纳米颗粒的室温快速制备[J].无机化学学报,2021,37(10):1853-1861. |
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