| 室温快速合成一种钴基金属有机框架材料纳米颗粒用于高效氧析出 |
| Rapid Synthesis of Co-Based Metal-Organic Framework Nanoparticle at Room Temperature for Efficient Oxygen Evolution Reaction |
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| 摘要: 采用一种在室温下快速、温和的方法制备Co-MOF-74纳米颗粒，该纳米颗粒结晶度好、形貌均匀，可在碱性介质中实现高效电催化析氧反应（OER）。相较于传统的水热合成法，通过引入三乙胺大大降低了合成所需时间，只需室温下搅拌2 h即可得到Co-MOF-74纳米颗粒（约20 nm）。该纳米催化剂呈现出更高的比表面积（760 m2·g-1）、良好的OER活性和稳定性，在10 mA·cm-2的电流密度下过电势仅为275 mV。 |
| 关键词: 金属有机框架材料 纳米颗粒 快速合成 电催化析氧反应 |
| 基金项目: 国家自然科学基金（No.51202127）、湖北省自然科学基金（No.2016CFB382）、中央高校基本科研业务费专项资金（No.042017kf0227，2042019kf0205）资助。 |
| Abstract: A fast and mild method was developed to prepare Co-MOF-74 nanoparticles with high crystallinity and uniform morphology at room temperature for efficient oxygen evolution reaction (OER) in alkaline media. Compared with the conventional hydrothermal route, the time required for synthesis was greatly reduced after introducing triethylamine:Co-MOF-74 nanoparticles (about 20 nm) could be readily available by stirring at room temperature for only 2 h. The nano-electrocatalyst exhibited a larger specific surface area (760 m2·g-1), excellent activities and stability for OER with an overpotential of 275 mV to achieve a current density of 10 mA·cm-2. |
| Keywords: metal-organic frameworks nanoparticle rapid synthesis electrocatalytic oxygen evolution reaction |
| 投稿时间：2021-05-01 修订日期：2021-09-08 |
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| 贾宏男,姚娜,丛恒将.室温快速合成一种钴基金属有机框架材料纳米颗粒用于高效氧析出[J].无机化学学报,2021,37(11):2011-2019. |
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