| 基于(+)-二对甲基苯甲酰-D-酒石酸和铜(Ⅱ)构筑的配位聚合物的结构、热稳定性、荧光和染料吸附性质 | |
| Structure, Thermostability, Fluorescence, and Dye Adsorption Properties of a Copper(Ⅱ) Coordination Polymer Based on (+)-Di-p-toluoyl-D-tartaric Acid | |
| 摘要: 合成了一种配位聚合物{[Cu（HDTTA）2（DMF）（H2O）]·DMF·H2O}n（1）（D-H2DTTA=（+）-二对甲基苯甲酰-D-酒石酸，DMF=N，N-二甲基甲酰胺）。通过红外光谱、元素分析、X射线单晶衍射和粉末衍射表征了配合物1的结构。配合物1沿a轴为一维链状结构，在ab平面通过弱相互作用形成二维层状结构。热稳定性研究表明配合物1的主结构可在197℃以下稳定存在。在300 nm激发波长条件下，配体的荧光由于和Cu2+离子配位而猝灭。配合物1对水溶液中亚甲基蓝染料表现出良好的特异性吸附效果，作用49 min后吸附率可达81%。 | |
| 关键词: 铜(Ⅱ)配合物 (+)-二对甲基苯甲酰-D-酒石酸 晶体结构 荧光 染料吸附 | |
| 基金项目: 山西省1331工程重点创新研究团队、山西省自然科学基金（No.201901D111014）和山西省归国留学基金（No.2020-001）资助 | |
| Abstract: A coordination polymer, formulated as {[Cu(HDTTA) 2(DMF) (H2O)]·DMF·H2O}n (1) (D-H2DTTA=(+)-di-p-toluoyl-D-tartaric acid, DMF=N, N-dimethylformamide), has been synthesized. Its structure was characterized by IR spectrum, elemental analysis, X-ray single-crystal diffraction, and powder X-ray diffraction. Complex 1 features a 1D chain structure along the a-axis and forms a 2D layered structure in the ab plane through weak intermolecular interactions. The thermal decomposition process of 1 included the loss of solvent molecules below 197℃ and follow-up decomposition of the main structure. Under the excitation of 300 nm, the fluorescence of the ligand was quenched by the coordinated Cu2+ cation. In addition, complex 1 exhibited a good and specific adsorption effect on methylene blue dye in an aqueous solution with an adsorption rate of 81% after 49 min. | |
| Keywords: copper(Ⅱ) complex (+)-di-p-toluoyl-D-tartaric acid crystal structure fluorescence dye adsorption | |
| 投稿时间：2021-12-01 修订日期：2022-03-13 | |
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| 郑欢,褚衍潇,冯思思,袁彩霞.基于(+)-二对甲基苯甲酰-D-酒石酸和铜(Ⅱ)构筑的配位聚合物的结构、热稳定性、荧光和染料吸附性质[J].无机化学学报,2022,38(6):1112-1120. | |
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