WS2/CuGa2O4复合材料的制备及其气敏性
Preparation and gas-sensing properties of WS2/CuGa2O4 composite materials
作者单位E-mail
王春水 安徽工业大学化学与化工学院, 马鞍山 243032  
白玉莹 安徽工业大学化学与化工学院, 马鞍山 243032  
刘醒醒 安徽工业大学化学与化工学院, 马鞍山 243032  
李佳豪 安徽工业大学化学与化工学院, 马鞍山 243032  
储向峰 安徽工业大学化学与化工学院, 马鞍山 243032 maschem@sohu.com 
梁士明 临沂大学材料科学与工程学院, 临沂 276000 lsmwind@163.com 
摘要: 采用共沉淀法制备了CuGa2O4纳米材料,并利用水热法制备了一系列WS2/CuGa2O4复合材料。结合X射线衍射(XRD)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)等对制备的材料进行了物相组成、表面形貌以及元素价态的分析。研究了WS2的复合量对CuGa2O4材料检测乙醇气体敏感性能的影响。实验结果表明,当WS2与CuGa2O4质量比为1%时,该复合材料制备的传感器在室温下对100 μL·L-1乙醇气体表现出345.3的灵敏度,响应时间和恢复时间分别为184和69 s,且最低检测限为0.1μL·L-1
关键词: WS2  CuGa2O4  气敏性能  乙醇
基金项目: 国家自然科学基金(No.61971003)和山东省自然科学基金(No.ZR2020MF025)资助。
Abstract: CuGa2O4 nanomaterials were synthesized by the co-precipitation method, and a series of WS2/CuGa2O4 composite materials were prepared by the hydrothermal method. The crystal phase, morphology, and chemical state of the as-prepared materials were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and so on. The effect of the doped amount of WS2 on the gas-sensing sensitivity of CuGa2O4 materials to ethanol gas was studied. The results showed that when the mass ratio of WS2 to CuGa2O4 was 1%, the response of this gas sensor to 100 μL·L-1 ethanol gas at room temperature was 345.3, and the response and recovery times were 184 and 69 s, the detection limit reached 0.1 μL·L-1.
Keywords: WS2  CuGa2O4  gas sensing  ethanol
投稿时间:2023-02-13 修订日期:2023-05-05
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王春水,白玉莹,刘醒醒,李佳豪,储向峰,梁士明.WS2/CuGa2O4复合材料的制备及其气敏性[J].无机化学学报,2023,39(8):1519-1526.
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