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| Synthesis,Structure and Reactivity of a Trinuclear Ruthenium Cluster Compound[PyCH=C (Ph) O]2Ru3(CO)8 |
| Author Name | Affiliation | E-mail | | MA Zhi-Hong | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China
College of Basic Medicine, Hebei Medical University, Shijiazhuang 050017, China | | | LIU Qian | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China | | | QIN Mei | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China | qinmei2005@126.com | | HAN Zhan-Gang | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China | | | ZHENG Xue-Zhong | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China | | | LIN Jin | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China | linjin64@126.com |
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| Abstract: The title compound,[PyCH=C (Ph) O]2Ru3(CO)8(1),was obtained from the reaction of PyCH2COPh with Ru3(CO)12 in refluxing toluene.Compound 1 was characterized by IR,1H NMR,and 13C NMR spectroscopy as well as by single-crystal X-ray diffraction analysis.X-ray study of the cluster compound 1 shows that the three ruthenium atoms define an isosceles triangle with two distances of 0.280 nm and one of 0.307 nm.When 1 was treated with cyclopentadiene in refluxing toluene,dinuclear metal carbonyl complexes[(η5-C5H5) Ru (CO)]2(μ-CO)2(2) was obtained.Similar treatment of 1 with indene gave the product[(η5-C9H7) Ru (CO)]2(μ-CO)2(3). |
| Keywords: synthesis characterization metal carbonyl cluster compound reactivity |
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| MA Zhi-Hong,LIU Qian,QIN Mei,HAN Zhan-Gang,ZHENG Xue-Zhong,LIN Jin.Synthesis,Structure and Reactivity of a Trinuclear Ruthenium Cluster Compound[PyCH=C (Ph) O]2Ru3(CO)8[J].Chinese Journal of Inorganic Chemistry,2017,33(7):1293-1298. |
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