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| Second-Harmonic Generation and Two-Photon Activity of MOFs Modified by Organic Cationic Dyes |
| Author Name | Affiliation | E-mail | | HU Zhi-Yong | Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China | | | XU Sha-Sha | Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China | | | ZHANG Qiong | Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China | | | LI Sheng-Li | Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China | | | WU Jie-Ying | Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China | | | TIAN Yu-Peng | Department of Chemistry, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230601, China
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China | yptian@ahu.edu.cn |
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| Abstract: Novel composites with nonlinear optical effect were prepared by exchanging the dimethylamine cation with DB and TM in MOFs (ZJU-28) channels. DB or TM cations with strong polar were arranged along one direction in crystal pores, leading to non-central symmetric crystal. Compared to original ZJU-28, the composite crystals, DB@ZJU-28 and TM@ZJU-28, possess strong second harmonic generation (SHG) and two-photon absorption fluorescence observed through confocal microscopy. |
| Keywords: metal organic framework ZJU-28 host-guest interactions second-harmonic generation two-photon excitation fluorescence |
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| HU Zhi-Yong,XU Sha-Sha,ZHANG Qiong,LI Sheng-Li,WU Jie-Ying,TIAN Yu-Peng.Second-Harmonic Generation and Two-Photon Activity of MOFs Modified by Organic Cationic Dyes[J].Chinese Journal of Inorganic Chemistry,2017,33(11):2017-2023. |
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