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Preparation and Characterization of AlF3 Coated Natural Graphite Anode Materials
Author NameAffiliationE-mail
ZHOU Hai-Hui BTR New Energy Materials Inc., Shenzhen 518106, China hhzhou@btrchina.com 
WU Xuan BTR New Energy Materials Inc., Shenzhen 518106, China  
ZHOU Chen-Kun BTR New Energy Materials Inc., Shenzhen 518106, China  
REN Jian-Guo BTR New Energy Materials Inc., Shenzhen 518106, China  
Abstract: AlF3 coated Natural graphite composite (AF/NG) was synthesized by high speed mechanical dispersion and spray drying with the natural graphite as raw material. On the one hand, a more stable SEI film can be formed with the help of AlF3, which promoting the cycle performance. on the other hand, the AlF3 can promote the diffusion of lithium ions between the particles, which is benefit to the rate capability. AF/NG delivered a reversible capacity more than 278 mAh·g-1 at 0.5C, with a capacity of 78 mAh·g-1 higher than the uncoated sample (NG). The synthetic process is easy to control which is suitable for large-scale commercial production.
Keywords: AlF3  natural graphite  anode material  lithium-ion battery
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ZHOU Hai-Hui,WU Xuan,ZHOU Chen-Kun,REN Jian-Guo.Preparation and Characterization of AlF3 Coated Natural Graphite Anode Materials[J].Chinese Journal of Inorganic Chemistry,2018,34(4):676-682.
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Chinese Journal of Inorganic Chemistry