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| Mononuclear Dy（III） and Ho（III） Complexes with Slow Magnetic Relaxation Behavior |
| Author Name | Affiliation | E-mail | | LI Dong-Ping | Department of Chemistry, Nanchang University, Nanchang 330031, China | nculdp@126.com | | WANG Qian | Department of Chemistry, Nanchang University, Nanchang 330031, China | | | XIE Yi-Bu | Department of Chemistry, Nanchang University, Nanchang 330031, China | | | ZHANG Jun | Key Laboratory of Functional Molecule Design and Interface Process, Anhui Jianzhu University, Hefei 230022, China | | | LIAN Qing-Yun | Department of Chemistry, Nanchang University, Nanchang 330031, China | | | LI Yong-Xiu | Department of Chemistry, Nanchang University, Nanchang 330031, China | yxli@ncu.edu.cn |
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| Abstract: Two new lanthanide complexes based on Schiff base ligand, namely[Dy(salen)2]3·3C2H9N2·2CH3OH (1) and[Ho(salen)2]3·3C2H9N2·1.5CH3OH (2), (H2salen=N,N'-bis(3-methoxysalicylidene)ethylene-1,2-diamine), have been synthesized and characterized. Single-crystal X-ray diffractions reveal that 1 and 2 crystallize in the same monoclinic space group C2, and have similar coordination environment around the metallic centers. Single molecule magnets (SMMs) behaviors have been observed in 1 and 2 with/without an applied magnetic field. |
| Keywords: Lanthanide complex crystal structure single-molecule magnet |
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| LI Dong-Ping,WANG Qian,XIE Yi-Bu,ZHANG Jun,LIAN Qing-Yun,LI Yong-Xiu.Mononuclear Dy（III） and Ho（III） Complexes with Slow Magnetic Relaxation Behavior[J].Chinese Journal of Inorganic Chemistry,2018,34(8):1547-1554. |
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