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| Syntheses, Crystal Structures and Spectral Properties of Cu(II), Cd(II) Complexes with 2-Methyl-5-(2-pyridyl)-1,3,4-oxadiazole |
| Author Name | Affiliation | E-mail | | BU De-Yan | College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China | | | GUO Yan-Hong | College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China | | | ZHENG Tao | College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China | | | SUN Ai-Jing | College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China | | | WANG Zuo-Xiang | College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China | wangzx0908@aliyun.com |
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| Abstract: 2-Methyl-5-(2-pyridyl)-1,3,4-oxadiazole(L),[Cu2L2(μ-Cl)2Cl2] (1) and[CdL2(NO3)2] (2) were synthesized and characterized by single crystal X-ray diffraction, IR, UV-Vis, fluorescence and TGA. Ligand L and complex 2 crystallize in monoclinic system. Complex 1 crystallizes in triclinic system. The space groups of compound L, complexes 1 and 2 are P21/c, P1 and C2/c, respectively. Complex 1 is a binuclear Cu(II) complex bridged by two Cl atoms (Cl1, Cl1i) and has a distorted tetragonal pyramidal geometry with[CuCl3N2]. Complex 2 has a distorted octahedral geometry with[CdN4O2]. |
| Keywords: crystal structure 1,3,4-oxadiazole synthesis Cu(II),Cd(II)complexes |
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| BU De-Yan,GUO Yan-Hong,ZHENG Tao,SUN Ai-Jing,WANG Zuo-Xiang.Syntheses, Crystal Structures and Spectral Properties of Cu(II), Cd(II) Complexes with 2-Methyl-5-(2-pyridyl)-1,3,4-oxadiazole[J].Chinese Journal of Inorganic Chemistry,2018,34(10):1875-1882. |
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