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One-Pot Synthesis of Rose-like Ce-Doped SnS2 with Enhanced Visible-Light Photocatalytic Property for Reduction of Cr(Ⅵ) |
Author Name | Affiliation | E-mail | LI Guo-Hui | College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China | | SUN Yuan-Yuan | College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China | sunyuanyuan@hainnu.edu.cn | XING Hua-Long | College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China | | ZHENG Jian-Cong | College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China | | LIN Chen-Chen | College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China | | SUN Zhen-Fan | College of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, China | sun@hainnu.edu.cn |
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Abstract: The Ce-doped SnS2 samples were prepared successfully through a one-pot hydrothermal method under mild conditions. The as-prepared SnS2 samples were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM) equipped with Energy dispersive X-ray Spectroscopy (EDS) which confirmed the doping of Ce. The results indicated the spiral growth mode and rose-like morphology of the samples. The effects of Ce doping on the photoabsorption, band gap, the potential of conduction band and the separation efficiency of photo-induced carriers were checked by diffuse reflectance spectrum (DRS) and electrochemical examinations. The reductive abilities of the samples were evaluated by the reduction of Cr(Ⅵ) chosen as a model pollutant. The results reveal that photocatalytic properties of Ce/SnS2 were strongly dependent on the proportion of Ce ions and the optimum doping amount of Ce is 5% (n/n). |
Keywords: doping photocatalysis reduction of Cr(Ⅵ) electrochemistry energy band structure |
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LI Guo-Hui,SUN Yuan-Yuan,XING Hua-Long,ZHENG Jian-Cong,LIN Chen-Chen,SUN Zhen-Fan.One-Pot Synthesis of Rose-like Ce-Doped SnS2 with Enhanced Visible-Light Photocatalytic Property for Reduction of Cr(Ⅵ)[J].Chinese Journal of Inorganic Chemistry,2019,35(2):194-202. |
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