|
| Influences of cis-, trans-1,2-Cyclohexanediamine Configurations on Iodoantimonate Organic-Inorganic Hybrid Isomers |
| Author Name | Affiliation | E-mail | | LIANG Zhi-Wen | College of Chemistry, Nanchang University, Nanchang 330031, China | | | CHEN Xiao-Rou | College of Chemistry, Nanchang University, Nanchang 330031, China | | | YU Hui | College of Chemistry, Nanchang University, Nanchang 330031, China | | | WEI Zhen-Hong | College of Chemistry, Nanchang University, Nanchang 330031, China | weizh@ncu.edu.cn | | ZHANG Xiu-Xiu | College of Chemistry, Nanchang University, Nanchang 330031, China | | | CAI Hu | College of Chemistry, Nanchang University, Nanchang 330031, China | |
|
| Abstract: Reactions of cis-and trans-1,2-cyclohexanediamine (DAC) with antimony iodide in concentrated HI aqueous solution afforded two organic-inorganic hybrid isomers (cis-1,2-DACH2)[SbI5]·H2O (1) and {(trans-1,2-DACH2)[SbI5]·H2O}n (2), respectively. The single-crystal X-ray diffraction revealed that the inorganic component in compound 1 is a dimer[Sb2I10] built up from two[SbI6] octahedra by sharing I-I edge, and that in compound 2 is a zigzag chain constructed with corner-sharing octahedral[SbI6] units. In addition, both compounds have been investigated and compared by UV-Vis, fluorescent spectra, and DFT calculation. |
| Keywords: 1,2-cyclohexanediamine antimony iodide cis-and trans-configuration organic-inorganic hybrid crystal structure |
| Hits: 1697 |
| Download times: 643 |
| LIANG Zhi-Wen,CHEN Xiao-Rou,YU Hui,WEI Zhen-Hong,ZHANG Xiu-Xiu,CAI Hu.Influences of cis-, trans-1,2-Cyclohexanediamine Configurations on Iodoantimonate Organic-Inorganic Hybrid Isomers[J].Chinese Journal of Inorganic Chemistry,2019,35(2):337-343. |
| View Full Text View/Add Comment Download reader |
|
|
|
|
|
|
|
|
