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Honeycomb-like Carbon Materials Derived from Pomelo Peels for the Simultaneous Detection of Heavy Metal Ions
Author NameAffiliationE-mail
ZHANG Ting College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China  
MA Shi-Jie College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China  
PAN Yi College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China  
GUAN Ji-Biao College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China  
ZHANG Ming College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China  
ZHU Han Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China  
DU Ming-Liang Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China du@jiangnan.edu.cn 
Abstract: The metal-free carbon materials were obtained by a facile KOH activation and pyrolysis process from inexpensive and readily available pomelo peels, and possessed honeycomb-like nanostructures with a high specific surface area of 1 055 m2·g-1 and a high graphitization degree. A porous activated carbon (PAC) material modified electrode was utilized as the working electrode for the simultaneous detection of Cd2+, Pb2+, and Cu2+ using square-wave anodic stripping voltammetry (SWASV) and exhibited high sensitivity, repeatability, stability and a low detection limit. The interconnected micropores and mesopores act as efficient ion-transfer channels and provid active surface areas with high accessibility, which serve as transport highways to accelerate mass diffusion and significantly promote exchange efficiency. High graphitization degree increases the electrical conductivity of the material and accelerates electron transport.
Keywords: carbonaceous materials  pomelo peels  honeycomb-like nanostructures  porous materials  heavy metal ion detection  square-wave anodic stripping voltammetry (SWASV)
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ZHANG Ting,MA Shi-Jie,PAN Yi,GUAN Ji-Biao,ZHANG Ming,ZHU Han,DU Ming-Liang.Honeycomb-like Carbon Materials Derived from Pomelo Peels for the Simultaneous Detection of Heavy Metal Ions[J].Chinese Journal of Inorganic Chemistry,2019,35(4):674-686.
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Chinese Journal of Inorganic Chemistry