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Honeycomb-like Carbon Materials Derived from Pomelo Peels for the Simultaneous Detection of Heavy Metal Ions |
Author Name | Affiliation | E-mail | ZHANG Ting | College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China | | MA Shi-Jie | College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China | | PAN Yi | College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China | | GUAN Ji-Biao | College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China | | ZHANG Ming | College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China | | ZHU Han | Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China | | DU Ming-Liang | Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China | du@jiangnan.edu.cn |
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Abstract: The metal-free carbon materials were obtained by a facile KOH activation and pyrolysis process from inexpensive and readily available pomelo peels, and possessed honeycomb-like nanostructures with a high specific surface area of 1 055 m2·g-1 and a high graphitization degree. A porous activated carbon (PAC) material modified electrode was utilized as the working electrode for the simultaneous detection of Cd2+, Pb2+, and Cu2+ using square-wave anodic stripping voltammetry (SWASV) and exhibited high sensitivity, repeatability, stability and a low detection limit. The interconnected micropores and mesopores act as efficient ion-transfer channels and provid active surface areas with high accessibility, which serve as transport highways to accelerate mass diffusion and significantly promote exchange efficiency. High graphitization degree increases the electrical conductivity of the material and accelerates electron transport. |
Keywords: carbonaceous materials pomelo peels honeycomb-like nanostructures porous materials heavy metal ion detection square-wave anodic stripping voltammetry (SWASV) |
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ZHANG Ting,MA Shi-Jie,PAN Yi,GUAN Ji-Biao,ZHANG Ming,ZHU Han,DU Ming-Liang.Honeycomb-like Carbon Materials Derived from Pomelo Peels for the Simultaneous Detection of Heavy Metal Ions[J].Chinese Journal of Inorganic Chemistry,2019,35(4):674-686. |
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