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Preparation and Electrocatalytic Performance of Flake Co9S8/ZnS/C Composites for Oxygen Evolution Reduction
Author NameAffiliationE-mail
LI Zhi-Xue College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, Liaoning 113006, China  
REN Tie-Qiang College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, Liaoning 113006, China  
GENG Zhong-Xing College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, Liaoning 113006, China  
YANG Zhan-Xu College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun, Liaoning 113006, China zhanxuy@126.com 
Abstract: The flake Co9S8/ZnS/C composites were prepared by solvothermal method, through using cobalt hexahydrate[Co(NO3)2·6H2O] as cobalt source, zinc hexahydrate nitrate[Zn(NO3)2·6H2O] as zinc source and 2,2'-thiodiacetic acid (C4H6O4S) as sulfur source. The flake Co9S8/ZnS/C composites structure and morphology were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N2 adsorption-desorption test. Meanwhile, the results of electrocatalytic oxygen evolution reaction for the flake Co9S8/ZnS/C composite showed that it had high electrocatalytic oxygen production performance, with the initial overpotential of 390 mV and the Tafel slope of 144 mV·dec-1.
Keywords: Co9S8/C  ZnS  transition metal  water splitting  oxygen evolution reaction  solvothermal method
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LI Zhi-Xue,REN Tie-Qiang,GENG Zhong-Xing,YANG Zhan-Xu.Preparation and Electrocatalytic Performance of Flake Co9S8/ZnS/C Composites for Oxygen Evolution Reduction[J].Chinese Journal of Inorganic Chemistry,2019,35(12):2318-2322.
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Chinese Journal of Inorganic Chemistry