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Preparation of Porous Silicon Nanomaterials and Applications in High Energy Lithium Ion Batteries
Author NameAffiliationE-mail
SUN Lin School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
Key Laboratory of Mesoscopic Chemistry of MOE, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
Jiangsu Province Cultivation base for State Key Laboratory of Photovoltaic Science and Technology, Changzhou University, Changzhou, Jiangsu 213164, China 
 
XIE Jie School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China  
LIU Tao School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China  
HUANG Song-Chao School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China  
ZHANG Lei School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China  
CHEN Zhi-Dong Jiangsu Province Cultivation base for State Key Laboratory of Photovoltaic Science and Technology, Changzhou University, Changzhou, Jiangsu 213164, China  
JIANG Rui-Yu School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China jaingry@ycit.edu.cn 
JIN Zhong School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
Key Laboratory of Mesoscopic Chemistry of MOE, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China 
zhongjin@nju.edu.cn 
Abstract: Porous silicon nanomaterials hold great promise in the fields of drug therapy, sensors and energy storage and conversion due to their high specific surfaces areas and tunable physicochemical properties. Especially in the area of high energy lithium ion batteries, porous silicon has attracted many concerns owning to the abundant pore channels, which will effectively releasing the huge stress that induced by the volume change and shorten the lithium ion transport distance. However, developing rapid and convenient methods for preparing structure tunable porous silicon still remain challenge. In recent years, some feasible strategies have been proposed and developed to synthesize porous silicon. Based on the recent developments, this review detailedly summarizes the current popular approaches that have been employed in the preparation of porous silicon, as well as the applications in high energy lithium ion batteries. Finally, some directions that can further promote the development of porous silicon have also been proposed.
Keywords: silicon  synthesis design  etching method  metal reduction  lithium ion battery  anode material  materials science
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SUN Lin,XIE Jie,LIU Tao,HUANG Song-Chao,ZHANG Lei,CHEN Zhi-Dong,JIANG Rui-Yu,JIN Zhong.Preparation of Porous Silicon Nanomaterials and Applications in High Energy Lithium Ion Batteries[J].Chinese Journal of Inorganic Chemistry,2020,36(3):393-405.
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Chinese Journal of Inorganic Chemistry