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Adsorption of rhodamine B by benzimidazole-based metal-organic framework/graphene oxide composites
Author NameAffiliationE-mail
HAN Xiao Hebei Key Laboratory of Heterocyclic Compounds, Hebei Center for New Inorganic Optoelectronic Nanomaterial Research, College of Chemical Engineering & Material, Handan University, Handan, Hebei 056005, China hanxiao2007510806@126.com 
WANG Lin-Yu Hebei Key Laboratory of Heterocyclic Compounds, Hebei Center for New Inorganic Optoelectronic Nanomaterial Research, College of Chemical Engineering & Material, Handan University, Handan, Hebei 056005, China  
GENG Fu-Jiang Hebei Key Laboratory of Heterocyclic Compounds, Hebei Center for New Inorganic Optoelectronic Nanomaterial Research, College of Chemical Engineering & Material, Handan University, Handan, Hebei 056005, China  
XI Gai-Qing Hebei Key Laboratory of Heterocyclic Compounds, Hebei Center for New Inorganic Optoelectronic Nanomaterial Research, College of Chemical Engineering & Material, Handan University, Handan, Hebei 056005, China xigq2005@163.com 
Abstract: In this work, two different morphologies of composites with Cd (Ⅱ) benzimidazole-derived metal-organic framework (MOF) and graphene oxide (GO) were successfully synthesized by adjusting the alkali environments in the one-pot solvothermal process. The structures and properties of these composites were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-visible absorption spectra (UV-Vis), and FT-IR. The adsorption performance of these composites for rhodamine B (RhB) in water was studied. The results showed that GO and Cd-MOF were successfully combined, and the addition of GO enhanced the stability of Cd-MOF in water and improved its adsorption capacity. When the pH value of the solution was 3.5 and the adsorption time was 60 min, the adsorption rate could reach ca. 95%.
Keywords: composite  adsorption  rhodamine B
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HAN Xiao,WANG Lin-Yu,GENG Fu-Jiang,XI Gai-Qing.Adsorption of rhodamine B by benzimidazole-based metal-organic framework/graphene oxide composites[J].Chinese Journal of Inorganic Chemistry,2023,39(6):1159-1168.
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Chinese Journal of Inorganic Chemistry