|
| Effect of free water molecule in copper complexes on the performance of light absorption and adsorption of Cr（Ⅵ） |
| Author Name | Affiliation | E-mail | | YANG Shao-Long | School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
School of Mechanical and Resource Engineering, Wuzhou University, Wuzhou, Guangxi 543003, China | | | CHEN Yu-Huan | School of Mechanical and Resource Engineering, Wuzhou University, Wuzhou, Guangxi 543003, China | | | YAN Mu-Lun | School of Mechanical and Resource Engineering, Wuzhou University, Wuzhou, Guangxi 543003, China | | | WEI Cheng-Ting | School of Mechanical and Resource Engineering, Wuzhou University, Wuzhou, Guangxi 543003, China | | | LI Shi-Xiong | School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China
School of Mechanical and Resource Engineering, Wuzhou University, Wuzhou, Guangxi 543003, China | lsx1324@163.com | | JIA Bing-Jing | School of Mechanical and Resource Engineering, Wuzhou University, Wuzhou, Guangxi 543003, China | |
|
| Abstract: Cu(ClO4)2·6H2O and (1-methyl-1H-benzimidazol-2-yl) methanol (HL) reacted in a mixed solution of methanol and acetonitrile to produce dark blue[Cu(HL)3](ClO4)2·H2O (1) and light blue[Cu(HL)3](ClO4)2 (2). Their structures were characterized by elemental analysis, IR, thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. The test results showed that complexes 1 and 2 are both composed of[Cu(HL)3]2+ and the counter anion ClO4-, except for the addition of one free water molecule in 1. The Cu（Ⅱ） ions in 1 and 2 are coordinated with N and O atoms from the HL; the coordination number was six. The results of TGA showed that the structures of 1 and 2 could remain unchanged in a range of 30-245℃. However, complex 1 with a dark blue color had a wider absorption peak at 289 nm compared to 2 with a light blue color. The adsorption experiment showed that 1 exhibited better adsorption performance for Cr（Ⅵ） than 2 at pH=4-8. It can be seen that the free water molecule in 1 has a certain impact on light absorption and the adsorption of Cr（Ⅵ）. |
| Keywords: complex crystal structure performance effect |
| Hits: 1606 |
| Download times: 1056 |
| YANG Shao-Long,CHEN Yu-Huan,YAN Mu-Lun,WEI Cheng-Ting,LI Shi-Xiong,JIA Bing-Jing.Effect of free water molecule in copper complexes on the performance of light absorption and adsorption of Cr（Ⅵ）[J].Chinese Journal of Inorganic Chemistry,2023,39(11):2160-2168. |
| View Full Text View/Add Comment Download reader |
|
|
|
|
|
|
|
|
