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Preparation and triethylamine sensing performance of ZnSnO3/NiO heterostructures
Author NameAffiliationE-mail
DU Liyong Department of Materials and Chemical Engineering, Taiyuan University, Taiyuan 030032, China 495431287@qq.com,duliyong@tyu.edu.cn 
LIU Yi School of Physics and Optoelectronic Engineering, Hainan University, Haikou 570228, China  
YANG Guoli Department of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, Shanxi 030619, China galiyang@126.com 
Abstract: In this study, ZnSnO3/NiO heterostructures were synthesized using a co-precipitation method followed by an annealing process. The gas-sensitive characteristics of the sensors based on these samples were evaluated. The results indicate that the sensor performance was optimized when the molar ratio of Ni to Zn was 1∶2. Specifically, the response values of the ZnSnO3/NiO-2-based sensor to 100 μL·L-1 triethylamine (TEA) gas at 220 ℃ reached 70.6, which were 6.1 times higher than that of the pure ZnSnO3 based sensor. The findings demonstrate that ZnSnO3/ NiO heterostructures exhibited not only short response and recovery times (1 s/18 s) but also good gas selectivity, repeatability, and long-term stability. The enhanced sensing mechanism has been investigated in detail.
Keywords: heterostructures  ZnSnO3/NiO  triethylamine  gas sensing performance  gas sensing mechanism
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DU Liyong,LIU Yi,YANG Guoli.Preparation and triethylamine sensing performance of ZnSnO3/NiO heterostructures[J].Chinese Journal of Inorganic Chemistry,2025,41(4):729-740.
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Chinese Journal of Inorganic Chemistry