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Preparation and photocatalytic performance of CsxWO3/TiO2 based on full spectral resp
Author NameAffiliationE-mail
LIU Zhangyong School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China  
XU Lihui School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China
National Innovation Center of Advanced Dyeing & Finishing Technology, Tai'an, Shandong 271000, China 
xulh0915@163.com 
YANG Yue Shanghai Aurora Vocational College, Shanghai 201908, China  
WANG Liming School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China
National Innovation Center of Advanced Dyeing & Finishing Technology, Tai'an, Shandong 271000, China 
 
PAN Hong School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China
National Innovation Center of Advanced Dyeing & Finishing Technology, Tai'an, Shandong 271000, China 
 
HUANG Xinzhe School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China  
FU Xueqiang School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China  
ZHANG Yingxiu School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China  
DOU Meiran School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China  
WANG Meng School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China  
TENG Yi School of Textiles and Fashion, Shanghai University of Engineering Science, Shanghai 201620, China  
Abstract: CsxWO3/TiO2 composites with full-spectrum catalytic activity were prepared by solvothermal reaction. The composites were characterized using X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), specific surface area testing, X-ray photoelectron spectroscopy (XPS), and UV-Vis diffuse reflectance spectra (UV-Vis DRS). CsxWO3 and TiO2 were uniformly bonded together in the composites. The heterojunction structure was formed. The band gap was reduced from 2.75 to 2.65 eV. The photocatalytic property of CsxWO3/TiO2 was demonstrated by the degradation rates of 20 mg·L-1 methylene blue dye, which were 99.7%, 91.4%, and 70.7% under irradiation from a 300 W high-pressure mercury lamp, a 500 W xenon lamp, and a 400 W infrared lamp, respectively. After five cycles of photocatalytic degradation, the composite photocatalyst still showed a degradation efficiency of 87.6%. This indicates that CsxWO3/TiO2 has good photocatalytic degradability and cyclic stability. The photocatalytic mechanism of CsxWO3/TiO2 was investigated. The trapping experiments of the active species showed that the main active substances were the empty hole (h+) and hydroxyl radical (·OH).
Keywords: CsxWO3-based  solvothermal method  full spectrum  composite material  photocatalytic activity
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LIU Zhangyong,XU Lihui,YANG Yue,WANG Liming,PAN Hong,HUANG Xinzhe,FU Xueqiang,ZHANG Yingxiu,DOU Meiran,WANG Meng,TENG Yi.Preparation and photocatalytic performance of CsxWO3/TiO2 based on full spectral resp[J].Chinese Journal of Inorganic Chemistry,2025,41(7):1445-1464.
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Chinese Journal of Inorganic Chemistry