| 有机钛化学——Ⅱ.二氯—双(2—甲氧乙基茂基)钛的合成与晶体结构 |
| ORGANOTITANIUM CHEMISTRY——II. SYNTHESIS AND CRYSTAL STRUCTURE OF BIS (2-METHOXYETHYLCYCLOPENTADIENYL) TITANIUM DICHLORIDE |
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| 摘要: 合成了标题化合物,为紫色晶体,用X射线衍射法测定了晶体结构。主要数据:单针晶系,空间群C2h5-P12/a,晶胞参数a=11.431(1), b=7,116(1),c=21.135(4)Å,β= 99.50(1)°,最终偏差因子R为0.046. |
| 关键词: 钛 配合物 晶体结构 |
| 基金项目: |
| Abstract: The title complex has been synthesized and its crystal structure has been determined by X-ray diffraction. The complex forms violet red crystals,which belong to monoclinic,with a=11.431(1),b=7.116(1),c=21.135(4)Å,β=99.50(1)°,space group C2h5-P15/a,2=4. The structure was solved by direct method and refined to final R=0.046 (for 1829 observed reflections). |
| Keywords: titanium complex crystal structure |
| 投稿时间：1985-07-05 |
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| 黄其辰,钱延龙,徐维铧,邵美成,唐有祺.有机钛化学——Ⅱ.二氯—双(2—甲氧乙基茂基)钛的合成与晶体结构[J].无机化学学报,1985,1(1):166-168. |
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