| 二吡啶四硝基酞菁钴的合成及光谱—电化学性质研究 |
| SYNTHESIS AND SPECTRO-ELECTROCHEMICAL STUDY OF COMPLEXES OF TETRANITROPHTHALOCYANINATO BIS(PYRIDINE)COBALT(Ⅱ) |
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| 摘要: 本文报道了以钼酸铵为催化剂,将4—硝基邻苯二甲酸酐、脲和氯化铵混合,于220℃加热合成四硝基酞菁钴,将此配合物溶于吡啶,于115℃加热反应6天合成了二吡啶四硝基酞菁钻配合物.并对二吡啶四硝基酞菁钴的氧化还原半波电势、电解氧化还原产物的电子吸收光谱进行了研究. |
| 关键词: 钴 四硝基酞菁 合成 光谱—电化学 |
| 基金项目: |
| Abstract: Tetranitrophthalocyaninato cobalt(I)(CoTNPc)was synthesised by mixing 4-nitrophthalic anhydride with urea, cobalt(I)chloride, ammonium chloride and ammonium molybdate and heating the mixture at 220℃ for 3 hrs. Under stirring CoTNPc reacts with pyridine for 6 days at temperatures 115℃ and the tetranitrophthalocyaninato bis(pyridine)cobalt(I)(CoTNPc(py)2)was obtained.In order to study the properties of CoTNPc(py)2, the half-wave potential and UV/vis spectra for the electrolytic products of oxidation-reduction of CoTNPc(py)2 were measured respectively. |
| Keywords: cobalt(Ⅱ) tetranitrophthalocyanine synthesis spectro-electrochemistry |
| 投稿时间：1986-06-23 |
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| 吴星,胡效亚.二吡啶四硝基酞菁钴的合成及光谱—电化学性质研究[J].无机化学学报,1987,3(2):117-121. |
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