| 二元中性体系对金(Ⅲ)的协同萃取研究 Ⅱ. TBP+DPSO的苯溶液协萃金(Ⅲ)及其机理 |
| STUDIES ON SYNERGIC EXTRACTION OF GOLD(Ⅲ)BY BINARY NEUTRAL SYSTEM(Ⅱ)SYNERGIC EXTRACTION OF GOLD(Ⅲ)WITH TBP AND DPSO IN BENZENE SOLUTION AND ITS MECHANISM |
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| 摘要: 本文研究磷酸三丁酯(TBP)与二苯基亚砜(DPSO)组成的二元中性体系(B-B体系)在HCl介质中对金(Ⅲ)的萃取行为,发现该体系有明显的协同萃取效应.用斜率法和紫外光谱法确定了协萃配合物的组成为H3O+·2TBP·DPSO·yH2O……AuCl4-·HCl.协萃反应的平衡常数log K1,2′=3.33.对协萃反应的机理和可能的结构也进行了讨论. |
| 关键词: 协同萃取 金 磷酸三丁酯 二苯基亚砜 |
| 基金项目: 中国科学院科学基金资助的课题 |
| Abstract: The synergic extraction of gold(Ⅲ)from hydrochloric acid medium with mixtures of tributyl phosphate(TBP)and diphenyl sulfoxide(DPSO)in benzene has been investigated.The formation of the extracted species H3O+·2TBP·DPSO·yH2O…AuCl4-·HCl is confirmed by slope analysis and UV spectra. The equilibrium constant of the extraction reaction log K1,2′=3.33 is calculated. |
| Keywords: synergic reaction gold TBP DPSO |
| 投稿时间：1986-09-16 |
| 摘要点击次数: 1160 |
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| 龚钰秋,姜美春,夏世华.二元中性体系对金(Ⅲ)的协同萃取研究 Ⅱ. TBP+DPSO的苯溶液协萃金(Ⅲ)及其机理[J].无机化学学报,1987,3(4):60-68. |
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