| 硫代钼酸盐和硫代钨酸盐的合成性质和取代反应的研究 |
| STUDY ON SYNTHESIS, PROPERTIES AND SUBSTITUTION REACTIONS OF THIOMOLYBDATE AND THIQTUNG STATE |
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| 摘要: 本文提出了在水或水/醇溶液中[NH4]2[MOnS4-n](M=Mo、W,n=0-2)进行取代反应的方法.用该方法合成出[X]2[MOnS4-n](X=(n-Bu)4N、Ph4P、py—C16H33共18个化合物,其中11个为新化合物,并采用元素分析、红外光谱、电子光谱和X-粉末衍射等方法对这些化合物进行了表征. |
| 关键词: 硫代铝酸盐 硫代钨酸盐 取代反应 |
| 基金项目: |
| Abstract: This paper reports the preparation of [NH4]2[MOnS4-n](M=Mo or W, n=0-2)in solution or in aqueous/alcohol solution by substitution reaction method. The reaction condition is mild and yields are generally good. Eighteen compounds with the formula, [X]M2 [MOnS4-n] [X=[n-Bu)4N, PhM4P, py-C18H33], have been prepared, of which 11 are new, characterized by chemical analysis, electronic spectra, IR spectra and X-ray powder diffraction. |
| Keywords: thiomolybdate thiotungstate substitution reaction |
| 投稿时间：1987-04-02 |
| 摘要点击次数: 1591 |
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| 金国新,忻新泉,陈汉文,郑兴福,戴安邦.硫代钼酸盐和硫代钨酸盐的合成性质和取代反应的研究[J].无机化学学报,1987,3(4):106-112. |
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