| 铁系元素冠醚配合物的研究——Ⅱ. 铁系氯化物与4'-碘苯并-15-冠-5固态配合物的合成与性质 |
| STUDIES ON IRON SERIES COORDINATION COMPOUNDS WITH CROWN ETHER II. SYNTHESIS AND PROPERTIES OF IRON SERTIES CHLORIDES WITH 4'-IODOBENZO-15-CROWN-5(L)COORDINATION COMPOUND IN SOLID STATE |
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| 摘要: <正>对碱金属、希土与苯并-15-冠-5冠醚配合物的研究[1-3]指出,4′-取代单苯并冠醚的阳离子配合物的稳定性及其他性质,受取代基电子效应的影响,给电性取代基可增加芳醚氧原子上的电子密度,改变冠氧的极性,从而影响其配位能力,扩大希土配合物之间性质上的差别,达到分离的目的.对于铁系元素,文献报导甚少.我们继Ⅰ[5]之后,又合成了三氯化铁水合物与4′-碘苯并-15-冠-5固态配合物,并研究了其性质. |
| 关键词: 铁系元素 配合物 冠醚配合物 |
| 基金项目: |
| Abstract: The synthesis and properties of coordination compounds of iron series chlorides(FeCl3·CoCl2 and NiCl2)with 4'-iodobenzo-15-crown-5 were reported in this paper.Synthesized FeCl3·L·3H2O is a new kind of 1:1 crown ether coordination compound. Which contains three moles crystal water and characterized by element analysis, IR spectrum, UV spectrum, DTA TG and X-ray.Under the same conditions, the coordination compounds of CoCl2 and NiC12 with 4'-iodobenzo-15-crown-5 were not formed. |
| Keywords: iron series element coordination compound crown ether coordination compound |
| 投稿时间：1986-10-03 |
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| 卢爱茹,张联祥,张卫锴,缪荣生,王流芳,晏国洪.铁系元素冠醚配合物的研究——Ⅱ. 铁系氯化物与4'-碘苯并-15-冠-5固态配合物的合成与性质[J].无机化学学报,1987,3(4):132-137. |
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