| 二茂铁基苯酰腙的d区金属螯合物的合成和表征 |
| SYNTHESIS AND CHARACTERIZATION FOR d-BLOCK METAL CHELATES OF FER-ROCENYL BENZOYL HYDRAZONE |
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| 摘要: 二茂铁基苯酰腙与d区金属乙酸盐或氯化物在乙醇中反应,得到了6个新的螯合物,分子式为M(Fcbh)n[Fcbh=Fc—C=N—N=C-C6H5,Fc=C5H5—FeC5H4;M=Cr(Ⅲ)、Fe(Ⅲ)时,n=3;M=Mn(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)时,n=2]和Pd(Fcbh—H)2Cl2[Fcbh—H=Fc—C=N—NHCOC |
| 关键词: 二茂铁基苯酰腙 d区金属螯合物 配位方式 |
| 基金项目: |
| Abstract: Six new chelates were synthesized via the reactions of transition metal acetates or chlorides with ferrocenyl benzoyl hydrazone. These chelates have been characterized by elemental analyses, IR, 1H NMR and mass spectra. Two different patterns in which the ligand C5H5FeC8H4-C=N-NH-C-C6H5 coordinates with d-block metals were described. |
| Keywords: ferrocenyl benzoyl hydrazone d-block metal chelates coordinate patterns |
| 投稿时间：1987-04-28 |
| 摘要点击次数: 1294 |
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| 方新钦,张伦,张铁灵.二茂铁基苯酰腙的d区金属螯合物的合成和表征[J].无机化学学报,1988,4(3):20-27. |
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