| 铁系元素冠醚配合物的研究——V.三氯化铁与4′-溴苯并-15-冠-5固态配合物的合成和性质 |
| STUDIES ON IRON SERIES COORDINATION COM POUNDS WITH CROWN ETHER Ⅴ. SYNTHESES AND PROPERTIES OF FERRIC CHLORIDE WITH 4'-BROMOBENZO-15-CROWN -5-ETHER SOLID COORDINATION COMPOUND |
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| 摘要: 本文报导了三氯化铁(水合物)与4′-溴苯并-15-冠-5(L)固态配合物的合成,对合成的新配合物,进行了元素定量分析及摩尔电导测定,并作了红外光谱、紫外光谱,热重和差热以及X-射线粉末衍射分析的性质表征。从而证明,该配合物中FeCl3与配体L比为1:1,是溶化剂,含有结晶水的固态配合物。 |
| 关键词: 铁系元素 配合物 冠醚配合物 |
| 基金项目: |
| Abstract: This paper reports the syntheses and properties of iron three halides with 4'-bromobenzo-15-crown-5-ether solid coordination compound.FeCl3·L·1/2CH3CN·2H2O synthesized is a new kind of crown ether coordination compound,in which FeCl3:L is equal to 1:1.It is solvatcd and it contains two moles crystal water.It was identified by elemental analysis,TR,UV,TG,DTA,mole conductance and X-ray powder diffraction analysis. |
| Keywords: iron series element coordination compound crown ether coordination compound |
| 投稿时间：1987-10-21 |
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| 张联祥,卢爱茹,张有明,董芳.铁系元素冠醚配合物的研究——V.三氯化铁与4′-溴苯并-15-冠-5固态配合物的合成和性质[J].无机化学学报,1989,5(1):115-118. |
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